Thorium dioxide

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Thorium dioxide
Other names Thorium(IV) oxide
Thoria
Thorianite
Identifiers
InChI InChI=1/2O.Th/q2*-2;+4
InChIKey DNNLEMIRRGUGOZ-UHFFFAOYAA
Standard InChI InChI=1S/2O.Th/q2*-2;+4
Standard InChIKey DNNLEMIRRGUGOZ-UHFFFAOYSA-N
CAS number [1314-20-1]
EC number 215-225-1
ChemSpider 148578
Properties[1]
Chemical formula ThO2
Molar mass 264.04 g mol−1
Appearance white solid
Density 9.86 g cm−3
Melting point

3220(50) °C

Boiling point

ca. 4400 °C

Solubility in water insoluble
Structure[2]
Space group Fm3m
Lattice constant a = 559.2 pm
Thermochemistry[3]
Std enthalpy of formation ΔfHo298 −1226.4(35) kJ mol−1
Standard molar entropy So298 65.23(20) J K−1 mol−1
Related compounds
Other anions Thorium disulfide
Thorium diselenide
Thorium ditelluride
Other cations Protactinium dioxide
Uranium dioxide
Zirconium dioxide
Hafnium dioxide
Other compounds Thorium monoxide
Thorium sesquioxide
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Thorium dioxide, ThO2, also known as thoria, is the main oxide of thorium.

Notes and references

Notes

References

  1. CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-157. ISBN 0-8493-0462-8
  2. Wickleder, Mathias S.; Fourest, Blandine; Dorhout, Peter K. Thorium. In The Chemistry of the Actinide and Transactinide Elements, 3rd ed.; Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, Eds.; Springer: Dordrecht, the Netherlands, 2006; Vol. 1, Chapter 3, pp 52–160. doi:10.1007/1-4020-3598-5_3, <http://radchem.nevada.edu/classes/rdch710/files/thorium.pdf>.
  3. Thorium dioxide. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3D1S/2O.Th>. (accessed 9 January 2011).

External links

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