Difference between revisions of "Cyclopentadienylthallium"
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| IUPACName = Thallium(I) cyclopentadienide | | IUPACName = Thallium(I) cyclopentadienide | ||
| − | | OtherNames = Thallium cyclopentadienide; ( | + | | OtherNames = Thallium cyclopentadienide; (η<sup>5</sup>-cyclopentadienyl)thallium |
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
| ChemSpiderID = 24721800 | | ChemSpiderID = 24721800 | ||
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| Section2 = {{Chembox Properties | | Section2 = {{Chembox Properties | ||
| Formula = C<sub>5</sub>H<sub>5</sub>Tl | | Formula = C<sub>5</sub>H<sub>5</sub>Tl | ||
| + | | MolarMass = 269.48 g mol<sup>−1</sup> | ||
| Appearance = yellow solid | | Appearance = yellow solid | ||
| Density = | | Density = | ||
Revision as of 14:35, 18 December 2010
| Cyclopentadienylthallium | |
|---|---|
| |
| IUPAC name | Thallium(I) cyclopentadienide |
| Other names | Thallium cyclopentadienide; (η5-cyclopentadienyl)thallium |
| Identifiers | |
| InChI | InChI=1/C5H5.Tl/c1-2-4-5-3-1;/h1-5H;/q-1;+1 |
| InChIKey | CVEQRUADOXXBRI-UHFFFAOYAE |
| Standard InChI | InChI=1S/C5H5.Tl/c1-2-4-5-3-1;/h1-5H;/q-1;+1 |
| Standard InChIKey | CVEQRUADOXXBRI-UHFFFAOYSA-N |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties | |
| Chemical formula | C5H5Tl |
| Molar mass | 269.48 g mol−1 |
| Appearance | yellow solid |
| Solubility in water | insoluble |
| Hazards | |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Cyclopentadienylthallium is an organothallium compound. It may be prepared by the reaction of aqueous thallium hydroxide solution with cyclopentadiene, from which mixture it precipitates as air-stable yellow crystals.[1]
The bonding mode of the cyclopentadienyl ligand is η5. In the gas phase, the compound is monomeric, with the thallium atom sitting 241 pm above the plane of the cyclopentadienyl ring,[1] while the crystal structure has zigzag chains of equidistant thallium cations and cyclopentadienide anions.[1]
