Difference between revisions of "Thionyl bromide"
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| − | '''Thionyl bromide''', SOBr<sub>2</sub>, is an orange-yellow liquid that fumes in moist air. | + | '''Thionyl bromide''', SOBr<sub>2</sub>, is an orange-yellow liquid that fumes in moist air. It is produced by passing anhydrous [[hydrogen bromide]] through [[thionyl chloride]],<ref name="Kirk-Othmer"/> and is used as a brominating agent in organic chemistry, e.g. for the conversion of [[alcohol]]s to [[bromoalkane]]s.<ref name="Kirk-Othmer"/> |
==Notes and references== | ==Notes and references== | ||
| Line 35: | Line 35: | ||
===References=== | ===References=== | ||
{{reflist}} | {{reflist}} | ||
| + | |||
| + | ===Further reading=== | ||
| + | *{{citation | first1 = Jon | last1 = Brunvoll | first2 = István | last2 = Hargittai | first3 = Béla | last3 = Rozsondai | title = The molecular structure of thionyl bromide by gas phase electron diffraction | journal = J. Mol. Struct. | volume = 84 | issue = 1–2 | year = 1982 | pages = 153–55 | doi = 10.1016/0022-2860(82)85119-3}}. | ||
| + | |||
| + | ==External links== | ||
| + | {{wikipedia|Thionyl bromide}} | ||
| + | {{commons|Thionyl bromide}} | ||
[[Category:Sulfur compounds]] | [[Category:Sulfur compounds]] | ||
Latest revision as of 12:23, 8 January 2011
| Thionyl bromide | |
|---|---|
| Other names | Thionyl dibromide Sulfur oxobromide |
| Identifiers | |
| InChI | InChI=1/Br2OS/c1-4(2)3 |
| InChIKey | HFRXJVQOXRXOPP-UHFFFAOYAY |
| Standard InChI | InChI=1S/Br2OS/c1-4(2)3 |
| Standard InChIKey | HFRXJVQOXRXOPP-UHFFFAOYSA-N |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties[1] | |
| Chemical formula | SOBr2 |
| Molar mass | 207.87 g mol−1 |
| Appearance | orange-yellow liquid |
| Density | 2.69 g cm−3 |
| Melting point |
−52 °C |
| Boiling point |
39 °C (2 kPa) |
| Solubility in water | reacts violently |
| Related compounds | |
| Other anions | Thionyl fluoride Thionyl chloride Thionyl iodide |
| Other cations | Selenium oxobromide Tellurium oxobromide |
| Other compounds | Disulfur dibromide Sulfuryl bromide |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Thionyl bromide, SOBr2, is an orange-yellow liquid that fumes in moist air. It is produced by passing anhydrous hydrogen bromide through thionyl chloride,[1] and is used as a brominating agent in organic chemistry, e.g. for the conversion of alcohols to bromoalkanes.[1]
Notes and references
Notes
References
- ↑ 1.0 1.1 1.2 Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
Further reading
- Brunvoll, Jon; Hargittai, István; Rozsondai, Béla The molecular structure of thionyl bromide by gas phase electron diffraction. J. Mol. Struct. 1982, 84 (1–2), 153–55. DOI: 10.1016/0022-2860(82)85119-3.
External links
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See also the corresponding article on Wikipedia. |
 |
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