Difference between revisions of "File:Digitoxigeninsynthesispartb.png"

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{{No license}}
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{{Fileinfo
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| description = Part of [[Nakada's synthesis of digitoxigenin]].
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| date =
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| source =
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| author =
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| permission =
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}}
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{{Substance identification
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| name = 4-(1-methylcyclohexa-2,5-dien-1-yl)-2-oxo-1-(phenylsulfonyl)butane-1-diazonium
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| InChI = 1/C17H18N2O3S/c1-17(11-6-3-7-12-17)13-10-15(20)16(19-18)23(​21,22)14-8-4-2-5-9-14/h2,4-9,11-12H,3,10,13H2,1H3/b16-15-
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| StdInChI = 1S/C17H18N2O3S/c1-17(11-6-3-7-12-17)13-10-15(20)16(19-18)23​(21,22)14-8-4-2-5-9-14/h2,4-9,11-12H,3,10,13H2,1H3/b16-15-
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| InChIKey = CNDCLZGIISMRGN-NXVVXOECBB
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| StdInChIKey = CNDCLZGIISMRGN-NXVVXOECSA-N
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|  InChI_ref = [http://www.chemspider.com/17229226 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (4''S'',4'''S'')-2,2'-propane-2,2-diylbis[4-(propan-2-yl)-4,5-dihydro-1,3-oxazole]
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| InChI = 1/C15H26N2O2/c1-9(2)11-7-18-13(16-11)15(5,6)14-17-12(8-19-1​4)10(3)4/h9-12H,7-8H2,1-6H3/t11-,12-/m1/s1
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| StdInChI = 1S/C15H26N2O2/c1-9(2)11-7-18-13(16-11)15(5,6)14-17-12(8-19-​14)10(3)4/h9-12H,7-8H2,1-6H3/t11-,12-/m1/s1
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| InChIKey = XFZUPCITFHSROM-VXGBXAGGBW
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| StdInChIKey = XFZUPCITFHSROM-VXGBXAGGSA-N
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|  InChI_ref = [http://www.chemspider.com/9996215 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (3a''R'',6a''R'')-6a-methyl-3a-(phenylsulfonyl)-1,3a,3b,4,6a,6b-hexahydrocyclopropa[''de'']naphthalen-3(2''H'')-one
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| InChI = 1/C17H18O3S/c1-16-10-5-8-13-15(16)17(13,14(18)9-11-16)21(19 ​,20)12-6-3-2-4-7-12/h2-7,10,13,15H,8-9,11H2,1H3/t13-,15-,16-,17-/​m0/s1
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| StdInChI = 1S/C17H18O3S/c1-16-10-5-8-13-15(16)17(13,14(18)9-11-16)21(1 ​9,20)12-6-3-2-4-7-12/h2-7,10,13,15H,8-9,11H2,1H3/t13-,15-,16-,17-​ /m0/s1
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| InChIKey = HSSHNGXBTFXHCM-HJWJTTGWBG
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| StdInChIKey = HSSHNGXBTFXHCM-HJWJTTGWSA-N
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|  InChI_ref = [http://www.chemspider.com/17229228 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (4a''S'',8a''R'')-4a-methyl-3,4,4a,7,8,8a-hexahydronaphthalen-2(1''H'')-one
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| InChI = 1/C11H16O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h3,6,9H,2,4-5,7​-8H2,1H3/t9-,11+/m1/s1
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| StdInChI = 1S/C11H16O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h3,6,9H,2,4-5,​7-8H2,1H3/t9-,11+/m1/s1
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| InChIKey = AZIVURUBLCCCKL-KOLCDFICBP
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| StdInChIKey = AZIVURUBLCCCKL-KOLCDFICSA-N
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|  InChI_ref = [http://www.chemspider.com/17229229 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (4a''S'',7''S'',8a''S'')-7-[''tert''-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalene
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| InChI = 1/C27H36OSi/c1-26(2,3)29(24-14-7-5-8-15-24,25-16-9-6-10-17-25)28-23-18-20-27(4)19-12-11-13-22(27)21-23/h5-10,12,14-17,19,22-23H,11,13,18,20-21H2,1-4H3/t22-,23+,27+/m1/s1
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| StdInChI =
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| InChIKey =
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| StdInChIKey =
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|  InChI_ref =
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = 1-(''tert''-butylperoxy)-1λ<sup>3</sup>,2-benziodoxol-3(1''H'')-one
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| InChI = 1/C11H13IO4/c1-11(2,3)15-16-12-9-7-5-4-6-8(9)10(13)14-12/h4​-7H,1-3H3
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| StdInChI = 1S/C11H13IO4/c1-11(2,3)15-16-12-9-7-5-4-6-8(9)10(13)14-12/h​4-7H,1-3H3
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| InChIKey = NATGCBBISNEFGA-UHFFFAOYAN
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| StdInChIKey = NATGCBBISNEFGA-UHFFFAOYSA-N
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|  InChI_ref = [http://www.chemspider.com/9221116 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (4a''S'',7''S'',8a''S'')-7-[''tert''-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalen-2-one
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| InChI = 1/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-14 ​-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,1​ 6,18-20H2,1-4H3/t21-,23+,27+/m1/s1
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| StdInChI = 1S/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-1 ​4-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,​ 16,18-20H2,1-4H3/t21-,23+,27+/m1/s1
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| InChIKey = YGGDIROWPHRHNN-ZYVVXELTBM
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| StdInChIKey = YGGDIROWPHRHNN-ZYVVXELTSA-N
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|  InChI_ref = [http://www.chemspider.com/17229170 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
  
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[[Category:Total syntheses]]

Latest revision as of 14:48, 16 August 2009

Exclamation red.png This file is lacking valid copyright license information. Please add this information, preferably in the form of a license tag, as soon as possible or the file may be deleted. See WikiChem:Copyrights for more details.
Description Part of Nakada's synthesis of digitoxigenin.
Date
Source
Author
Permission
Substance identification
This file contains an image or representation of, or data relating to, 4-(1-methylcyclohexa-2,5-dien-1-yl)-2-oxo-1-(phenylsulfonyl)butane-1-diazonium.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C17H18N2O3S/c1-17(11-6-3-7-12-17)13-10-15(20)16(19-18)23(​21,22)14-8-4-2-5-9-14/h2,4-9,11-12H,3,10,13H2,1H3/b16-15-
 InChI=1S/C17H18N2O3S/c1-17(11-6-3-7-12-17)13-10-15(20)16(19-18)23​(21,22)14-8-4-2-5-9-14/h2,4-9,11-12H,3,10,13H2,1H3/b16-15-
InChIKeys: CNDCLZGIISMRGN-NXVVXOECBB, CNDCLZGIISMRGN-NXVVXOECSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (4S,4'S)-2,2'-propane-2,2-diylbis[4-(propan-2-yl)-4,5-dihydro-1,3-oxazole].
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C15H26N2O2/c1-9(2)11-7-18-13(16-11)15(5,6)14-17-12(8-19-1​4)10(3)4/h9-12H,7-8H2,1-6H3/t11-,12-/m1/s1
 InChI=1S/C15H26N2O2/c1-9(2)11-7-18-13(16-11)15(5,6)14-17-12(8-19-​14)10(3)4/h9-12H,7-8H2,1-6H3/t11-,12-/m1/s1
InChIKeys: XFZUPCITFHSROM-VXGBXAGGBW, XFZUPCITFHSROM-VXGBXAGGSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (3aR,6aR)-6a-methyl-3a-(phenylsulfonyl)-1,3a,3b,4,6a,6b-hexahydrocyclopropa[de]naphthalen-3(2H)-one.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C17H18O3S/c1-16-10-5-8-13-15(16)17(13,14(18)9-11-16)21(19 ​,20)12-6-3-2-4-7-12/h2-7,10,13,15H,8-9,11H2,1H3/t13-,15-,16-,17-/​m0/s1
 InChI=1S/C17H18O3S/c1-16-10-5-8-13-15(16)17(13,14(18)9-11-16)21(1 ​9,20)12-6-3-2-4-7-12/h2-7,10,13,15H,8-9,11H2,1H3/t13-,15-,16-,17-​ /m0/s1
InChIKeys: HSSHNGXBTFXHCM-HJWJTTGWBG, HSSHNGXBTFXHCM-HJWJTTGWSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (4aS,8aR)-4a-methyl-3,4,4a,7,8,8a-hexahydronaphthalen-2(1H)-one.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C11H16O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h3,6,9H,2,4-5,7​-8H2,1H3/t9-,11+/m1/s1
 InChI=1S/C11H16O/c1-11-6-3-2-4-9(11)8-10(12)5-7-11/h3,6,9H,2,4-5,​7-8H2,1H3/t9-,11+/m1/s1
InChIKeys: AZIVURUBLCCCKL-KOLCDFICBP, AZIVURUBLCCCKL-KOLCDFICSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (4aS,7S,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalene.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C27H36OSi/c1-26(2,3)29(24-14-7-5-8-15-24,25-16-9-6-10-17-25)28-23-18-20-27(4)19-12-11-13-22(27)21-23/h5-10,12,14-17,19,22-23H,11,13,18,20-21H2,1-4H3/t22-,23+,27+/m1/s1
Substance identification
This file contains an image or representation of, or data relating to, 1-(tert-butylperoxy)-1λ3,2-benziodoxol-3(1H)-one.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C11H13IO4/c1-11(2,3)15-16-12-9-7-5-4-6-8(9)10(13)14-12/h4​-7H,1-3H3
 InChI=1S/C11H13IO4/c1-11(2,3)15-16-12-9-7-5-4-6-8(9)10(13)14-12/h​4-7H,1-3H3
InChIKeys: NATGCBBISNEFGA-UHFFFAOYAN, NATGCBBISNEFGA-UHFFFAOYSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (4aS,7S,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalen-2-one.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-14 ​-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,1​ 6,18-20H2,1-4H3/t21-,23+,27+/m1/s1
 InChI=1S/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-1 ​4-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,​ 16,18-20H2,1-4H3/t21-,23+,27+/m1/s1
InChIKeys: YGGDIROWPHRHNN-ZYVVXELTBM, YGGDIROWPHRHNN-ZYVVXELTSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider

File history

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current16:58, 7 May 2008Thumbnail for version as of 16:58, 7 May 20082,235 × 868 (51 KB)Jkloecker (talk | contribs)
16:49, 7 May 2008Thumbnail for version as of 16:49, 7 May 20082,230 × 868 (51 KB)Jkloecker (talk | contribs)
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