Difference between revisions of "Peroxydisulfuric acid"
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| OtherNames = Persulfuric acid | | OtherNames = Persulfuric acid | ||
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
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| InChI = 1/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) | | InChI = 1/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) | ||
| StdInChI = 1S/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) | | StdInChI = 1S/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) | ||
| InChIKey = JRKICGRDRMAZLK-UHFFFAOYAS | | InChIKey = JRKICGRDRMAZLK-UHFFFAOYAS | ||
| StdInChIKey = JRKICGRDRMAZLK-UHFFFAOYSA-N | | StdInChIKey = JRKICGRDRMAZLK-UHFFFAOYSA-N | ||
− | | | + | | CASNo = 13445-49-3 |
+ | | PubChem = 24413 | ||
+ | | ChEBI = 29268 | ||
}} | }} | ||
| Section2 = {{Chembox Properties | | Section2 = {{Chembox Properties | ||
− | | Reference = <ref name="G&E">{{Greenwood&Earnshaw1st|page=846}}.</ref> | + | | Reference = <ref name="G&E">{{Greenwood&Earnshaw1st|page=846}}.</ref><ref>{{RubberBible62nd|page=B-154}}.</ref> |
| H = 2 | S = 2 | O = 8 | | H = 2 | S = 2 | O = 8 | ||
− | | Appearance = colourless solid | + | | Appearance = colourless solid, hygroscopic |
| Density = | | Density = | ||
| MeltingPtC = 65 | | MeltingPtC = 65 | ||
| Melting_notes = decomp. | | Melting_notes = decomp. | ||
− | | | + | | Solubility = reacts |
− | | | + | | SolubleOther = soluble in [[ethanol]], [[diethyl ether]], [[sulfuric acid]] |
+ | }} | ||
+ | | Section 7 = {{Chembox Hazards | ||
+ | | EUIndex = not listed | ||
}} | }} | ||
− | | | + | | Section8 = {{Chembox Related |
| OtherCpds = [[Potassium persulfate]] | | OtherCpds = [[Potassium persulfate]] | ||
}} | }} |
Revision as of 18:44, 23 August 2009
Peroxydisulfuric acid | |
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IUPAC name | μ-peroxido-bis(hydroxidodioxidosulfur) peroxydisulfuric acid |
Other names | Persulfuric acid |
Identifiers | |
InChI | InChI=1/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) |
InChIKey | JRKICGRDRMAZLK-UHFFFAOYAS |
Standard InChI | InChI=1S/H2O8S2/c1-9(2,3)7-8-10(4,5)6/h(H,1,2,3)(H,4,5,6) |
Standard InChIKey | JRKICGRDRMAZLK-UHFFFAOYSA-N |
CAS number | [ | ]
PubChem | |
ChEBI | 29268 |
Properties[1][2] | |
Molecular formula | H2O8S2 |
Molar mass | 194.14 g mol−1 |
Appearance | colourless solid, hygroscopic |
Melting point |
65 °C, 338 K, 149 °F decomp. |
Solubility in water | reacts |
Solubility | soluble in ethanol, diethyl ether, sulfuric acid |
Related compounds | |
Other compounds | Potassium persulfate |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Peroxydisulfuric is a sulfur oxoacid with the chemical formula H2S2O8. In structural terms it can be written HO3SOOSO3H.[1] It is one of a group of sulfur oxoacids, its salts, commonly known as persulfates, are industrially important but the acid itself is not. The salts contain the peroxydisulfate ion, S2O82−, with O–O = 131 pm and S–Oµ = 150 pm.[1]
References
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