Difference between revisions of "Caesium cadmium chloride"

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(Imported from http://en.wikipedia.org/w/index.php?title=Caesium_cadmium_chloride&oldid=284331233)
 
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{{chembox
 
{{chembox
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|   Name = Caesium cadmium chloride
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| Name = Caesium cadmium chloride
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|   IUPACName = Caesium cadmium chloride
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| IUPACName = Caesium cadmium chloride
 
| Section2 = {{Chembox Properties
 
| Section2 = {{Chembox Properties
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|  Formula = [[Caesium|Cs]][[Cadmium|Cd]][[Chlorine|Cl<sub>3</sub>]]
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|  Formula = CsCdCl<sub>3</sub>
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|  MolarMass = 351.675 g/mol
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|  MolarMass = 351.68 g/mol
 
|  Appearance = White or colourless solid
 
|  Appearance = White or colourless solid
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  }}
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| Section3 = {{Chembox Structure
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|  Reference = <ref>{{citation | Electron paramagnetic resonance spectra of vanadium(II) and
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nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride | first1 = Jin Rong | last1 = Chang | first2 = Gary L. | last2 = McPherson | first3 = Jerry L. | last3 = Atwood | journal = Inorg. Chem. | year = 1975 | volume = 14 | issue = 12 | pages = 3079–85 | doi = 10.1021/ic50154a044}}.</ref>
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|  CrystalStruct = [[Hexagonal crystal system|Hexagonal]]
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|  SpaceGroup = P6<sub>3</sub>/mmc, No. 194
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|  LattConst_a = 740.3 pm
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|  LattConst_c = 1840.6 pm
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|  Coordination = Cd<sup>2+</sup>: D<sub>3d</sub>, C<sub>3v</sub>
 
   }}
 
   }}
 
}}
 
}}
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'''Caesium cadmium chloride''' (CsCdCl<sub>3</sub>) is a synthetic crystalline material. It belongs to the AMX<sub>3</sub> group (where A=alkali metal, M=bivalent metal, X=halogen ions). It crystallizes in a [[hexagonal crystal system|hexagonal]] [[space group]] <math>\mathrm{P}6_{3}/\mathrm{mmc}\,\!</math> with unit cell lengths ''a'' = 7.403 [[Angstroms|Å]] and ''c'' = 18.406 Å, with one cadmium ion having [[Schoenflies notation|''D<sub>3d</sub>'']] symmetry and the other having ''C<sub>3v</sub>'' symmetry<ref>Electron paramagnetic resonance spectra of vanadium(II) and
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'''Caesium cadmium chloride''' (CsCdCl<sub>3</sub>) is a synthetic crystalline material. It belongs to the AMX<sub>3</sub> group, where A&nbsp;= an alkali metal, M&nbsp;= a bivalent metal and X&nbsp;= a halide. It is formed from an [[aqueous]] solution of [[hydrochloric acid]] containing [[Stoichiometry|equimolar]] quantities of [[caesium chloride]] and [[cadmium chloride]].<ref>{{citation | title = Electron paramagnetic spectrum of manganese(II)–manganese(II)
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nickel(II) doped into crystals of cesium cadmium chloride and
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pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer | first1 = Gary L. | last1 = McPherson | first2 = Jin Rong | last2 = Chang | journal = Inorg. Chem. | year = 1976 | volume = 15 | issue = 5 | pages = 1018–22 | doi = 10.1021/ic50159a006}}.</ref>
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a redetermination of the structure of cesium cadmium chloride.
 
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Jin Rong Chang, Gary L. McPherson, and Jerry L. Atwood,
 
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Inorg. Chem., 1975, 14 (12), 3079-3085. DOI: 10.1021/ic50154a044</ref>.
 
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It is formed when an [[aqueous]] solution of [[hydrochloric acid]] containing an [[wikt:equimolar|equimolar]] solution of [[caesium chloride]] and [[cadmium chloride]]<ref>Electron paramagnetic spectrum of manganese(II)-manganese(II)
 
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pairs in single crystals of cesium cadmium chloride.
 
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Electronic structure of the nonachlorodimanganate(5-) dimer
 
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Gary L. McPherson, and Jin Rong Chang,
 
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Inorg. Chem., 1976, 15 (5), 1018-1022. DOI: 10.1021/ic50159a006</ref>.
 
  
 
==References==
 
==References==
 
{{reflist}}
 
{{reflist}}
  
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[[Category:Metal halides]]
 
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[[Category:Crystals]]
 
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[[Category:Optical materials]]
 
 
[[Category:Caesium compounds]]
 
[[Category:Caesium compounds]]
 
[[Category:Cadmium compounds]]
 
[[Category:Cadmium compounds]]
 
[[Category:Chlorides]]
 
[[Category:Chlorides]]
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[[Category:Metal halides]]
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[[Category:Optical materials]]
  
 
{{Imported from Wikipedia|name=Caesium cadmium chloride|id=284331233}}
 
{{Imported from Wikipedia|name=Caesium cadmium chloride|id=284331233}}

Revision as of 19:32, 24 August 2009

Caesium cadmium chloride
IUPAC name Caesium cadmium chloride
Properties
Chemical formula CsCdCl3
Molar mass 351.68 g/mol
Appearance White or colourless solid
Structure[1]
Crystal structure Hexagonal
Space group P63/mmc, No. 194
Lattice constant a = 740.3 pm, c = 1840.6 pm
Coordination geometry Cd2+: D3d, C3v
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group, where A = an alkali metal, M = a bivalent metal and X = a halide. It is formed from an aqueous solution of hydrochloric acid containing equimolar quantities of caesium chloride and cadmium chloride.[2]

References

  1. ↑ Chang, Jin Rong; McPherson, Gary L.; Atwood, Jerry L. Inorg. Chem. 1975, 14 (12), 3079–85. DOI: 10.1021/ic50154a044.
  2. ↑ McPherson, Gary L.; Chang, Jin Rong [http://dx.doi.org/10.1021%2Fic50159a006 Electron paramagnetic spectrum of manganese(II)–manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer]. Inorg. Chem. 1976, 15 (5), 1018–22. DOI: 10.1021/ic50159a006.
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