Difference between revisions of "Caesium cadmium chloride"

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'''Caesium cadmium chloride''' (CsCdCl<sub>3</sub>) is a synthetic crystalline material. It belongs to the AMX<sub>3</sub> group, where A&nbsp;= an alkali metal, M&nbsp;= a bivalent metal and X&nbsp;= a halide. It is formed from an [[aqueous]] solution of [[hydrochloric acid]] containing  [[Stoichiometry|equimolar]] quantities of [[caesium chloride]] and [[cadmium chloride]].<ref>{{citation | title = Electron paramagnetic spectrum of manganese(II)–manganese(II)
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'''Caesium cadmium chloride''' (CsCdCl<sub>3</sub>) is a synthetic crystalline material. It belongs to the AMX<sub>3</sub> group, where A&nbsp;= an alkali metal, M&nbsp;= a bivalent metal and X&nbsp;= a halide. It is formed from an [[aqueous]] solution of [[hydrochloric acid]] containing  [[Stoichiometry|equimolar]] quantities of [[caesium chloride]] and [[cadmium chloride]].<ref>{{citation | title = Electron paramagnetic spectrum of manganese(II)–manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer | first1 = Gary L. | last1 = McPherson | first2 = Jin Rong | last2 = Chang | journal = Inorg. Chem. | year = 1976 | volume = 15 | issue = 5 | pages = 1018–22 | doi = 10.1021/ic50159a006}}.</ref>
pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer | first1 = Gary L. | last1 = McPherson | first2 = Jin Rong | last2 = Chang | journal = Inorg. Chem. | year = 1976 | volume = 15 | issue = 5 | pages = 1018–22 | doi = 10.1021/ic50159a006}}.</ref>
 
  
 
==References==
 
==References==

Revision as of 19:33, 24 August 2009

Caesium cadmium chloride
IUPAC name Caesium cadmium chloride
Properties
Chemical formula CsCdCl3
Molar mass 351.68 g/mol
Appearance White or colourless solid
Structure[1]
Crystal structure Hexagonal
Space group P63/mmc, No. 194
Lattice constant a = 740.3 pm, c = 1840.6 pm
Coordination geometry Cd2+: D3d, C3v
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group, where A = an alkali metal, M = a bivalent metal and X = a halide. It is formed from an aqueous solution of hydrochloric acid containing equimolar quantities of caesium chloride and cadmium chloride.[2]

References

  1. Chang, Jin Rong; McPherson, Gary L.; Atwood, Jerry L. Inorg. Chem. 1975, 14 (12), 3079–85. DOI: 10.1021/ic50154a044.
  2. McPherson, Gary L.; Chang, Jin Rong Electron paramagnetic spectrum of manganese(II)–manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer. Inorg. Chem. 1976, 15 (5), 1018–22. DOI: 10.1021/ic50159a006.
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