Difference between revisions of "Caesium cadmium chloride"
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| Section3 = {{Chembox Structure | | Section3 = {{Chembox Structure | ||
| − | | Reference = <ref>{{citation | Electron paramagnetic resonance spectra of vanadium(II) and | + | | Reference = <ref>{{citation | title = Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride | first1 = Jin Rong | last1 = Chang | first2 = Gary L. | last2 = McPherson | first3 = Jerry L. | last3 = Atwood | journal = Inorg. Chem. | year = 1975 | volume = 14 | issue = 12 | pages = 3079–85 | doi = 10.1021/ic50154a044}}.</ref> |
| − | nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride | first1 = Jin Rong | last1 = Chang | first2 = Gary L. | last2 = McPherson | first3 = Jerry L. | last3 = Atwood | journal = Inorg. Chem. | year = 1975 | volume = 14 | issue = 12 | pages = 3079–85 | doi = 10.1021/ic50154a044}}.</ref> | ||
| CrystalStruct = [[Hexagonal crystal system|Hexagonal]] | | CrystalStruct = [[Hexagonal crystal system|Hexagonal]] | ||
| SpaceGroup = P6<sub>3</sub>/mmc, No. 194 | | SpaceGroup = P6<sub>3</sub>/mmc, No. 194 | ||
Revision as of 19:36, 24 August 2009
| Caesium cadmium chloride | |
|---|---|
| IUPAC name | Caesium cadmium chloride |
| Properties | |
| Chemical formula | CsCdCl3 |
| Molar mass | 351.68 g/mol |
| Appearance | White or colourless solid |
| Structure[1] | |
| Crystal structure | Hexagonal |
| Space group | P63/mmc, No. 194 |
| Lattice constant | a = 740.3 pm, c = 1840.6 pm |
| Coordination geometry | Cd2+: D3d, C3v |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group, where A = an alkali metal, M = a bivalent metal and X = a halide. It is formed from an aqueous solution of hydrochloric acid containing equimolar quantities of caesium chloride and cadmium chloride.[2]
References
- ↑ Chang, Jin Rong; McPherson, Gary L.; Atwood, Jerry L. Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride. Inorg. Chem. 1975, 14 (12), 3079–85. DOI: 10.1021/ic50154a044.
- ↑ McPherson, Gary L.; Chang, Jin Rong Electron paramagnetic spectrum of manganese(II)–manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer. Inorg. Chem. 1976, 15 (5), 1018–22. DOI: 10.1021/ic50159a006.
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