Difference between revisions of "Caesium carbonate"
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| OtherNames = Cesium carbonate | | OtherNames = Cesium carbonate | ||
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
| − | | InChI = | + | | InChI = 1/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 |
| + | | StdInChI = 1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 | ||
| + | | InChIKey = FJDQFPXHSGXQBY-NUQVWONBAO | ||
| + | | StdInChIKey = FJDQFPXHSGXQBY-UHFFFAOYSA-L | ||
| CASNo = 534-17-8 | | CASNo = 534-17-8 | ||
| CASNo_Ref = {{cascite}} | | CASNo_Ref = {{cascite}} | ||
| − | | | + | | EC-number = 208-591-9 |
| + | | ChemSpiderID = 10339 | ||
| PubChem = | | PubChem = | ||
| RTECS = | | RTECS = | ||
| Line 39: | Line 43: | ||
{{reflist}} | {{reflist}} | ||
{{Unreferenced}} | {{Unreferenced}} | ||
| + | |||
| + | ==Further reading== | ||
| + | *{{citation | last1 = Crich | first1 = David | last2 = Banerjee | first2 = Abhisek | title = Expedient synthesis of ''threo''-β-hydroxy-α-amino acid derivatives: phenylalanine, tyrosine, histidine, and tryptophan | journal = J. Org. Chem. | year = 2006 | volume = 71 | issue = 18 | pages = 7106–9 | doi = 10.1021/jo061159i}}. | ||
| + | |||
| + | ==External links== | ||
| + | *{{OrgSynth preps|id=49137|name=caesium carbonate}} | ||
[[Category:Caesium compounds]] | [[Category:Caesium compounds]] | ||
Revision as of 20:20, 24 August 2009
| Caesium carbonate | |
|---|---|
| |
| IUPAC name | Caesium carbonate |
| Other names | Cesium carbonate |
| Identifiers | |
| InChI | InChI=1/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 |
| InChIKey | FJDQFPXHSGXQBY-NUQVWONBAO |
| Standard InChI | InChI=1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2 |
| Standard InChIKey | FJDQFPXHSGXQBY-UHFFFAOYSA-L |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties | |
| Chemical formula | Cs2CO3 |
| Molar mass | 325.82 g/mol |
| Appearance | white powder |
| Density | 4.072 g/cm3 |
| Melting point |
610 °C decomp. |
| Solubility in water | 260.5 g/100 mL (15 °C) |
| Hazards | |
| EU index number | not listed |
| Flash point | non-flammable |
| Related compounds | |
| Other cations | Lithium carbonate Sodium carbonate Potassium carbonate Rubidium carbonate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Caesium carbonate is a white crystalline solid of formula Cs2CO3. It is more soluble in organic solvents than many other carbonates such as potassium carbonate, and therefore finds use as a base in organic chemistry.
Characteristic of carbonate salts, it reacts with protic acids to give carbon dioxide gas, water, and a caesium salt as follows:
- Cs2CO3 + 2HCl -> 2CsCl + H2O + CO2
References
Further reading
- Crich, David; Banerjee, Abhisek Expedient synthesis of threo-β-hydroxy-α-amino acid derivatives: phenylalanine, tyrosine, histidine, and tryptophan. J. Org. Chem. 2006, 71 (18), 7106–9. DOI: 10.1021/jo061159i.
External links
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This page was originally imported from Wikipedia, specifically this version of the article "Caesium carbonate". Please see the history page on Wikipedia for the original authors. This WikiChem article may have been modified since it was imported. It is licensed under the Creative Commons Attribution–Share Alike 3.0 Unported license. |
