Difference between revisions of "Caesium hydride"
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{{Chembox | {{Chembox | ||
| − | | | + | | Name = Caesium hydride |
| − | | | + | | ImageFile = Caesium-hydride-xtal-3D-vdW.png |
| ImageSize = 200px | | ImageSize = 200px | ||
| − | | | + | | IUPACName = Caesium hydride |
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
| CASNo = 13772-47-9 | | CASNo = 13772-47-9 | ||
}} | }} | ||
| Section1 = {{Chembox Properties | | Section1 = {{Chembox Properties | ||
| − | | | + | | Reference = <ref>{{RubberBible62nd|page=B-92}}.</ref> |
| − | | MolarMass = 133. | + | | Formula = CsH |
| − | | Appearance = | + | | MolarMass = 133.91 g/mol |
| + | | Appearance = white solid | ||
| + | | Density = 3.41 g/cm<sup>3</sup> | ||
| + | | Solubility = reacts | ||
}} | }} | ||
| Section3 = {{Chembox Structure | | Section3 = {{Chembox Structure | ||
| − | | Coordination = Octahedral | + | | Coordination = Octahedral (Cs<sup>+</sup>)<br/>Octahedral (H<sup>−</sup>) |
| − | | CrystalStruct = [[ | + | | CrystalStruct = [[Sodium chloride structure|NaCl]], [[Pearson symbol|cF8]] |
| + | | SpaceGroup = Fm<u style="text-decoration:overline">3</u>m, No. 225 | ||
}} | }} | ||
| Section8 = {{Chembox Related | | Section8 = {{Chembox Related | ||
| − | | OtherAnions = [[Caesium fluoride | + | | OtherAnions = [[Caesium fluoride]]<br/>[[Caesium chloride]]<br/>[[Caesium bromide]]<br/>[[Caesium iodide|CsI]] |
| − | | OtherCations = [[Lithium hydride | + | | OtherCations = [[Lithium hydride]]<br/>[[Sodium hydride]]<br/>[[Potassium hydride]]<br/>[[Rubidium hydride]] |
}} | }} | ||
}} | }} | ||
'''Caesium hydride''' (CsH) is a compound of [[caesium]] and [[hydrogen]]. | '''Caesium hydride''' (CsH) is a compound of [[caesium]] and [[hydrogen]]. | ||
| − | It was the first substance to be create by light-induced particle formation in a metal vapor.<ref> | + | It was the first substance to be create by light-induced particle formation in a metal vapor.<ref>{{citation | first1 = A. | last1 = Tam | first2 = G. | last2 = Moe | first3 = W. | last3 = Happer | title = Particle Formation by Resonant Laser Light in Alkali-Metal Vapor | journal = Phys. Rev. Lett. | year = 1975 | volume = 35 | pages = 1630–33 | doi = 10.1103/PhysRevLett.35.1630}}.</ref> It also showed promise in early studies of an [[ion propulsion]] system using caesium.<ref>{{citation | last1 = Burkhart | first1 = J. A. | last2 = Smith | first2 = F. J. | title = Application of dynamic programming to optimizing the orbital control process of a 24-hour communications satellite | url = http://ntrs.nasa.gov/search.jsp?R=543868&id=2&qs=N%3D4294965816 | series = NASA Technical Report | date = November 1963}}.</ref> |
| − | The caesium nuclei in CsH can be hyperpolarized through interactions with an [[Optical Pumping|optically pumped]] caesium vapor in a process known as [[spin-exhcange optical pumping]] (SEOP). SEOP can increase the [[Nuclear Magnetic Resonance]] (NMR) signal of caesium nuclei by an order of magnitude.<ref> | + | The caesium nuclei in CsH can be hyperpolarized through interactions with an [[Optical Pumping|optically pumped]] caesium vapor in a process known as [[spin-exhcange optical pumping]] (SEOP). SEOP can increase the [[Nuclear Magnetic Resonance]] (NMR) signal of caesium nuclei by an order of magnitude.<ref>{{citation | first1 = K. | last1 = Ishikawa | first2 = B. | last2 = Patton | first3 = Y.-Y. | last3 = Jau | first4 = W. | last4 = Happer | title = Spin Transfer from an Optically Pumped Alkali Vapor to a Solid | journal = Phys. Rev. Lett. | year = 2007 | volume = 98 | page = 183004 | doi = 10.1103/PhysRevLett.98.183004}}.</ref> |
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==References== | ==References== | ||
| − | + | {{reflist}} | |
[[Category:Caesium compounds]] | [[Category:Caesium compounds]] | ||
Revision as of 07:54, 25 August 2009
| Caesium hydride | |
|---|---|
| |
| IUPAC name | Caesium hydride |
| Properties[1] | |
| Chemical formula | CsH |
| Molar mass | 133.91 g/mol |
| Appearance | white solid |
| Density | 3.41 g/cm3 |
| Solubility in water | reacts |
| Structure | |
| Crystal structure | NaCl, cF8 |
| Space group | Fm3m, No. 225 |
| Coordination geometry | Octahedral (Cs+) Octahedral (H−) |
| Related compounds | |
| Other anions | Caesium fluoride Caesium chloride Caesium bromide CsI |
| Other cations | Lithium hydride Sodium hydride Potassium hydride Rubidium hydride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Caesium hydride (CsH) is a compound of caesium and hydrogen. It was the first substance to be create by light-induced particle formation in a metal vapor.[2] It also showed promise in early studies of an ion propulsion system using caesium.[3]
The caesium nuclei in CsH can be hyperpolarized through interactions with an optically pumped caesium vapor in a process known as spin-exhcange optical pumping (SEOP). SEOP can increase the Nuclear Magnetic Resonance (NMR) signal of caesium nuclei by an order of magnitude.[4]
References
- ↑ CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-92. ISBN 0-8493-0462-8.
- ↑ Tam, A.; Moe, G.; Happer, W. Particle Formation by Resonant Laser Light in Alkali-Metal Vapor. Phys. Rev. Lett. 1975, 35, 1630–33. DOI: 10.1103/PhysRevLett.35.1630.
- ↑ Burkhart, J. A.; Smith, F. J. Application of dynamic programming to optimizing the orbital control process of a 24-hour communications satellite; NASA Technical Report, November 1963, <http://ntrs.nasa.gov/search.jsp?R=543868&id=2&qs=N%3D4294965816>.
- ↑ Ishikawa, K.; Patton, B.; Jau, Y.-Y.; Happer, W. Spin Transfer from an Optically Pumped Alkali Vapor to a Solid. Phys. Rev. Lett. 2007, 98, 183004. DOI: 10.1103/PhysRevLett.98.183004.
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