Difference between revisions of "Butyl PBD"

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| ImageFile = Butyl PBD.png
 
| ImageFile = Butyl PBD.png
 
| IUPACName = 2-(4-''tert''-Butylphenyl)-5-(4-phenylphenyl)-1,3,4-oxadiazole
 
| IUPACName = 2-(4-''tert''-Butylphenyl)-5-(4-phenylphenyl)-1,3,4-oxadiazole
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|  OtherNames = 2-(4-''tert''-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole<br/>2-(4-Biphenylyl)-5-(4-''tert''-butylphenyl)-1,3,4-oxadiazole
 
| Section1 = {{Chembox Identifiers
 
| Section1 = {{Chembox Identifiers
|  InChI=1/C24H22N2O/c1-24(2,3)21-15-13-20(14-16-21)23-26-25-22(27-23)19-11-9-18(10-12-19)17-7-5-4-6-8-17/h4-16H,1-3H3
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|  InChI={{InChIwrap|1/C24H22N2O/c1-24(2,3)21 -15-13-20(14-16-21)23-26-25-22( 27-23)19-11-9-18(10-12-19)17-7 -5-4-6-8-17/h4-16H,1-3H3}}
|  StdInChI=1S/C24H22N2O/c1-24(2,3)21-15-13-20(14-16-21)23-26-25-22(27-23)19-11-9-18(10-12-19)17-7-5-4-6-8-17/h4-16H,1-3H3
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|  StdInChI={{InChIwrap|1S/C24H22N2O/c1-24(2,3)2 1-15-13-20(14-16-21)23-26-25-22 (27-23)19-11-9-18(10-12-19)17- 7-5-4-6-8-17/h4-16H,1-3H3}}
 
|  InChIKey = XZCJVWCMJYNSQO-UHFFFAOYAT
 
|  InChIKey = XZCJVWCMJYNSQO-UHFFFAOYAT
 
|  StdInChIKey = XZCJVWCMJYNSQO-UHFFFAOYSA-N
 
|  StdInChIKey = XZCJVWCMJYNSQO-UHFFFAOYSA-N
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}}
 
}}
  
'''Butyl PBD''' or '''b-PBD''' is a [[Fluorescence|fluorescent]] organic compound used in the [[Liquid Scintillator Neutrino Detector]] at [[Los Alamos National Laboratory]], USA.<ref>{{citation | title = The Liquid Scintillator Neutrino Detector and LAMPF Neutrino Source | first1 = C. | last1 = Athanassopoulos | first2 = L. B. | last2 = Auerbach | first3 = D. | last3 = Bauer | first4 = R. D. | last4 = Bolton | first5 = R. L. | last5 = Burman | first6 = I. | last6 = Cohen | first7 = D. O. | last7 = Caldwell | first8 = B. D. | last8 = Dieterle | first9 = J. B. | last9 = Donahue | A. M. Eisner, A. Fazely, F. J. Federspiel, G. T. Garvey, M. Gray, R. M. Gunasingha, V. Highland, R. Imlay, K. Johnston, H. J. Kim, W. C. Louis, A. Lu, J. Margulies, G. B. Mills, K. McIlhany, W. Metcalf, R. A. Reeder, V. Sandberg, M. Schillaci, D. Smith, I. Stancu, W. Strossman, R. Tayloe, G. J. VanDalen, W. Vernon, Y-X. Wang, D. H. White, D. Whitehouse, D. Works, Y. Xiao, S. Yellin | journal = Nucl. Instrum. Meth. A | volume = 388 | pages = 149–72 | year = 1997 | doi = 10.1016/S0168-9002(96)01155-2 | arxiv = nucl-ex/9605002v1}}.</ref>
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'''Butyl PBD''' or '''b-PBD''' is a [[Fluorescence|fluorescent]] organic compound used in the [[Liquid Scintillator Neutrino Detector]] (LSND) at [[Los Alamos National Laboratory]], USA.<ref name="LSND">{{citation | title = The Liquid Scintillator Neutrino Detector and LAMPF Neutrino Source | first1 = C. | last1 = Athanassopoulos | first2 = L. B. | last2 = Auerbach | first3 = D. | last3 = Bauer | first4 = R. D. | last4 = Bolton | first5 = R. L. | last5 = Burman | first6 = I. | last6 = Cohen | first7 = D. O. | last7 = Caldwell | first8 = B. D. | last8 = Dieterle | first9 = J. B. | last9 = Donahue | first10 = A. M. | last10 = Eisner | first11 = A. | last11 = Fazely | first12 = F. J. | last12 = Federspiel | first13 = G. T. Garvey | last13 = M. Gray | first14 = R. M. | last14 = Gunasingha | first15 = V. | last15 = Highland | first16 = R. | last16 = Imlay | first17 = K. | last17 = Johnston | first18 = H. J. | last18 = Kim | first19 = W. C. | last19 = Louis | first20 = A. | last20 = Lu | first21 = J. | last21 = Margulies | first22 = G. B. | last22 = Mills | first23 = K. | last23 = McIlhany | first24 = W. | last24 = Metcalf | first25 = R. A. | last25 = Reeder | first26 = V. | last26 = Sandberg | first27 = M. | last27 = Schillaci | first28 = D. | last28 = Smith | first29 = I. | last29 = Stancu | first30 = W. | last30 = Strossman | first31 = R. | last31 = Tayloe | first32 = G. J. | last32 = Van Dalen | first33 = W. | last33 = Vernon | first34 = Y-X. | last34 = Wang | first35 = D. H. | last35 = White | first36 = D. | last36 = Whitehouse | first37 = D. | last37 = Works | first38 = Y. | last38 = Xiao | first39 = S. | last39 = Yellin | journal = Nucl. Instrum. Meth. A | volume = 388 | pages = 149–72 | year = 1997 | doi = 10.1016/S0168-9002(96)01155-2 | arxiv = nucl-ex/9605002v1}}.</ref>
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The fluorescent emission of b-PBD is at ''λ''<sub>em</sub>&nbsp;= 364&nbsp;nm for excitation at ''λ''<sub>ex</sub>&nbsp;= 305&nbsp;nm (in [[ethanol]] solution).<ref>{{citation | title = B8378 2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole ≥99% | url = http://www.sigmaaldrich.com/catalog/ProductDetail.do?D7=0&N5=Product%20No.|BRAND_KEY&N4=B8378|Sigma&N25=0&QS=ON&F=SPEC | publisher = Sigma-Aldrich | accessdate = 2010-05-22}}.</ref> As a scintillant in the LSND, it was used at a concentration of 31&nbsp;mg/l (87&nbsp;µmol/l) dissolved in [[mineral oil]].<ref name="LSND"/>
  
 
==References==
 
==References==
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==External links==
 
==External links==
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{{wikipedia|Butyl PBD}}
  
 
[[Category:Oxadiazoles]]
 
[[Category:Oxadiazoles]]
  
 
{{CC-BY-3.0}}
 
{{CC-BY-3.0}}

Latest revision as of 08:04, 23 May 2010

Butyl PBD
Butyl PBD.png
IUPAC name 2-(4-tert-Butylphenyl)-5-(4-phenylphenyl)-1,3,4-oxadiazole
Other names 2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole
2-(4-Biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole
Identifiers
InChI InChI=1/C24H22N2O/c1-24(2,3)21 -15-13-20(14-16-21)23-26-25-22( 27-23)19-11-9-18(10-12-19)17-7 -5-4-6-8-17/h4-16H,1-3H3
InChIKey XZCJVWCMJYNSQO-UHFFFAOYAT
Standard InChI InChI=1S/C24H22N2O/c1-24(2,3)2 1-15-13-20(14-16-21)23-26-25-22 (27-23)19-11-9-18(10-12-19)17- 7-5-4-6-8-17/h4-16H,1-3H3
Standard InChIKey XZCJVWCMJYNSQO-UHFFFAOYSA-N
CAS number [15082-28-7]
EC number 239-135-7
ChemSpider 76483
Properties
Chemical formula C24H22N2O
Molar mass 354.44 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Butyl PBD or b-PBD is a fluorescent organic compound used in the Liquid Scintillator Neutrino Detector (LSND) at Los Alamos National Laboratory, USA.[1]

The fluorescent emission of b-PBD is at λem = 364 nm for excitation at λex = 305 nm (in ethanol solution).[2] As a scintillant in the LSND, it was used at a concentration of 31 mg/l (87 µmol/l) dissolved in mineral oil.[1]

References

  1. 1.0 1.1 Athanassopoulos, C.; Auerbach, L. B.; Bauer, D.; Bolton, R. D.; Burman, R. L.; Cohen, I.; Caldwell, D. O.; Dieterle, B. D., et al. The Liquid Scintillator Neutrino Detector and LAMPF Neutrino Source. Nucl. Instrum. Meth. A 1997, 388, 149–72. DOI: 10.1016/S0168-9002(96)01155-2.
  2. B8378 2-(4-tert-Butylphenyl)-5-(4-biphenylyl)-1,3,4-oxadiazole ≥99%; Sigma-Aldrich, <http://www.sigmaaldrich.com/catalog/ProductDetail.do?D7=0&N5=Product%20No.>. (accessed 22 May 2010).

External links

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