Difference between revisions of "Lithium manganite"
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| Section3 = {{Chembox Structure | | Section3 = {{Chembox Structure | ||
| − | | Reference = <ref name="beta">{{citation | title = Zur Kenntnis der Oxomanganate(III): Über LiMnO<sub>2</sub> und β-NaMnO<sub>2</sub> | first1 = R. | last1 = Hoppe | first2 = G. | last2 = Brachtel | first3 = M. | last3 = Jansen | journal = Z. Anorg. Allg. Chem. | volume = 417 | issue = 1 | pages = 1–10 | doi = 10.1002/zaac.19754170102}}.</ref> | + | | Reference = <ref name="beta">{{citation | title = Zur Kenntnis der Oxomanganate(III): Über LiMnO<sub>2</sub> und β-NaMnO<sub>2</sub> | first1 = R. | last1 = Hoppe | first2 = G. | last2 = Brachtel | first3 = M. | last3 = Jansen | journal = Z. Anorg. Allg. Chem. | year = 1975 | volume = 417 | issue = 1 | pages = 1–10 | doi = 10.1002/zaac.19754170102}}.</ref> |
| CrystalStruct = Distorted [[Halite structure|halite (NaCl)]] | | CrystalStruct = Distorted [[Halite structure|halite (NaCl)]] | ||
| SpaceGroup = P''mnm'' | | SpaceGroup = P''mnm'' | ||
Revision as of 13:24, 26 June 2010
| Lithium manganite | |
|---|---|
| IUPAC name | lithium manganese dioxide |
| Properties | |
| Chemical formula | LiMnO2 |
| Molar mass | 93.878 g mol−1 |
| Structure[1] | |
| Crystal structure | Distorted halite (NaCl) |
| Space group | Pmnm |
| Lattice constant | a = 280(5) pm, b = 575(7) pm, c = 457(2) pm |
| Coordination geometry | Distorted octahedral (Li+, Mn3+) Distorted octahedral (O2−) |
| Related compounds | |
| Other anions | Lithium manganate Lithium permanganate |
| Other cations | Sodium manganite Potassium manganite |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Lithium manganite, LiMnO2, is a mixed oxide of lithium and manganese(III). It adopts a distorted halite (NaCl) structure in its two crystalline forms, with the MnO6 octahedra being distorted by the Jahn–Teller effect of the d4 Mn3+ cation.[1]
References
- ↑ 1.0 1.1 Hoppe, R.; Brachtel, G.; Jansen, M. Zur Kenntnis der Oxomanganate(III): Über LiMnO2 und β-NaMnO2. Z. Anorg. Allg. Chem. 1975, 417 (1), 1–10. DOI: 10.1002/zaac.19754170102.
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