Difference between revisions of "Raschig hydroxylamine process"
Physchim62 (talk | contribs) |
Physchim62 (talk | contribs) |
||
| Line 1: | Line 1: | ||
| − | The '''Raschig hydroxylamine process''' is an industrial process for producing [[hydroxylamine]], a modification of [[Fritz Raschig]]'s original synthesis of hydroxylamine.<ref>{{citation | last = Raschig | first = F. | title = Ueber das Verhalten der salpetrigen zur schwefligen Säure | journal = Ann. | volume = 241 | issue = 2 | pages = 161–252 | year = 1887 | doi = 10.1002/jlac.18872410202}}. {{citation | inventor-last = Raschig | inventor-first = Fritz | title = Verfahren zur Darstellung von Hydroxylamindisulfonsauren Alkalislatze und von Hydroxylamin aus letzteren | country-code = DE | patent-number = 41987 | issue-date = 1887-12-17}}.</ref> The hydroxylamine is generally used in the manufacture of [[caprolactam]] and hence [[nylon-6]], although it also finds use in the semiconductor industry. | + | The '''Raschig hydroxylamine process''' is an industrial process for producing [[hydroxylamine]], a modification of [[Fritz Raschig]]'s original synthesis of hydroxylamine.<ref>{{citation | last = Raschig | first = F. | title = Ueber das Verhalten der salpetrigen zur schwefligen Säure | journal = Justus Liebigs Ann. Chem. | volume = 241 | issue = 2 | pages = 161–252 | year = 1887 | doi = 10.1002/jlac.18872410202}}. {{citation | inventor-last = Raschig | inventor-first = Fritz | title = Verfahren zur Darstellung von Hydroxylamindisulfonsauren Alkalislatze und von Hydroxylamin aus letzteren | country-code = DE | patent-number = 41987 | issue-date = 1887-12-17}}.</ref> The hydroxylamine is generally used in the manufacture of [[caprolactam]] and hence [[nylon-6]], although it also finds use in the semiconductor industry. |
==Process chemistry== | ==Process chemistry== | ||
Revision as of 19:33, 3 July 2010
The Raschig hydroxylamine process is an industrial process for producing hydroxylamine, a modification of Fritz Raschig's original synthesis of hydroxylamine.[1] The hydroxylamine is generally used in the manufacture of caprolactam and hence nylon-6, although it also finds use in the semiconductor industry.
Process chemistry
The synthesis is a three step process. First, ammonia is oxidized in air to give nitrogen oxides (preferably dinitrogen trioxide), which react with ammonium carbonate to give ammonium nitrite:
- 2 NH3 + 3 O2 → N2O3 + 3 H2O
- N2O3 + (NH4)2CO3 → 2 NH4NO2 + CO2
The ammonium nitrite is reduced with sulfur dioxide in the presence of ammonia at 5 °C to give diammonium hydroxylaminedisulfonate:
- NH4NO2 + 2 SO2 + NH3 → (NH4)2[HON(SO3)2]
The disulfonate is then hydrolyzed at 100 °C to give hydroxylamine sulfate:
- 2 (NH4)2[HON(SO3)2] + 3 H2O → (NH3OH)2SO4 + 2 (NH4)2SO4
References
- ↑ Raschig, F. Ueber das Verhalten der salpetrigen zur schwefligen Säure. Justus Liebigs Ann. Chem. 1887, 241 (2), 161–252. DOI: 10.1002/jlac.18872410202. Raschig, Fritz Verfahren zur Darstellung von Hydroxylamindisulfonsauren Alkalislatze und von Hydroxylamin aus letzteren. DE Patent 41987, issued 17 December 1887.
External links
| Error creating thumbnail: Unable to save thumbnail to destination |
This page is currently licensed under the Creative Commons Attribution 3.0 Unported license and any later versions of that license. |
