Difference between revisions of "Bismuth trititanate"
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− | '''Bismuth | + | '''Bismuth trititanate''', Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>, is a [[mixed oxide]] of [[bismuth]] and [[titanium]]. It is [[Ferroelectricity|ferroelectric]], with a transition temperature of 675 °C, and has attracted substantial interest for [[lead]]-free high-temperature [[Piezoelectricity|piezoelectric]] devices. |
==Notes and references== | ==Notes and references== | ||
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*{{citation | first1 = Pusit | last1 = Pookmanee | first2 = Sukon | last2 = Phanichphant | title = Characterization of lead-free bismuth titanate (Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>) synthesized by a modified oxalate co-precipitation method | journal = J. Ceram. Process. Res. | volume = 10 | issue = 4 | pages = 448–52 | year = 2009 | url = http://jcpr.kbs-lab.co.kr/english/journal/JCPR/vol10num4/448.pdf}}. | *{{citation | first1 = Pusit | last1 = Pookmanee | first2 = Sukon | last2 = Phanichphant | title = Characterization of lead-free bismuth titanate (Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub>) synthesized by a modified oxalate co-precipitation method | journal = J. Ceram. Process. Res. | volume = 10 | issue = 4 | pages = 448–52 | year = 2009 | url = http://jcpr.kbs-lab.co.kr/english/journal/JCPR/vol10num4/448.pdf}}. | ||
*{{citation | last1 = Galasso | first1 = F. S. | last2 = Kestigan | first2 = M. | year = 2007 | title = Bismuth Titanate, Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> | journal = Inorg. Synth. | volume = 30 | pages = 121 | doi = 10.1002/9780470132616.ch24}}. | *{{citation | last1 = Galasso | first1 = F. S. | last2 = Kestigan | first2 = M. | year = 2007 | title = Bismuth Titanate, Bi<sub>4</sub>Ti<sub>3</sub>O<sub>12</sub> | journal = Inorg. Synth. | volume = 30 | pages = 121 | doi = 10.1002/9780470132616.ch24}}. | ||
+ | |||
+ | ==External links== | ||
+ | *{{UKPID|49|name=Bismuth}} | ||
[[Category:Bismuth compounds]] | [[Category:Bismuth compounds]] |
Latest revision as of 16:20, 8 January 2011
Bismuth trititanate | |
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IUPAC name | bismuth(III) oxide—titanium dioxide (2/3) |
Identifiers | |
InChI | InChI=1/4Bi.12O.3Ti/q4*+3;12*-1;;;/r4Bi.3O4Ti/c;;;;3*1-5(2,3)4/q4*+3;3*-4 |
InChIKey | KVNMYNXIQDOFRJ-OPDSCCRPAT |
Standard InChI | InChI=1S/4Bi.12O.3Ti/q4*+3;12*-1;;; |
Standard InChIKey | KVNMYNXIQDOFRJ-UHFFFAOYSA-N |
CAS number | [ | ]
EC number | |
ChemSpider | |
Properties | |
Chemical formula | Bi4Ti3O12 |
Molar mass | 1171.5 g mol−1 |
Appearance | white solid |
Structure | |
Coordination geometry | Octahedral (Ti4+) |
Hazards | |
EU index number | not listed |
Related compounds | |
Other anions | Bismuth dititanate bismuth tetratitanate |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Bismuth trititanate, Bi4Ti3O12, is a mixed oxide of bismuth and titanium. It is ferroelectric, with a transition temperature of 675 °C, and has attracted substantial interest for lead-free high-temperature piezoelectric devices.
Notes and references
Notes
References
Further reading
- Pookmanee, Pusit; Phanichphant, Sukon Characterization of lead-free bismuth titanate (Bi4Ti3O12) synthesized by a modified oxalate co-precipitation method. J. Ceram. Process. Res. 2009, 10 (4), 448–52, <http://jcpr.kbs-lab.co.kr/english/journal/JCPR/vol10num4/448.pdf>.
- Galasso, F. S.; Kestigan, M. Bismuth Titanate, Bi4Ti3O12. Inorg. Synth. 2007, 30, 121. DOI: 10.1002/9780470132616.ch24.
External links
- Bismuth: UK Poison Information Document
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