Difference between revisions of "Bismuth bromide"
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| StdInChIKey = PBKYCFJFZMEFRS-UHFFFAOYSA-L | | StdInChIKey = PBKYCFJFZMEFRS-UHFFFAOYSA-L | ||
| CASNo = 7787-58-8 | | CASNo = 7787-58-8 | ||
| − | | EINECS = | + | | EINECS = 232-121-1 |
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| Section2 = {{Chembox Properties | | Section2 = {{Chembox Properties | ||
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| Solubility = hydrolyzes | | Solubility = hydrolyzes | ||
| MeltingPt = 218 °C | | MeltingPt = 218 °C | ||
| − | | BoilingPt = 453 °C | + | | BoilingPt = 453 °C |
}} | }} | ||
| Section4 = {{Chembox Thermochemistry | | Section4 = {{Chembox Thermochemistry | ||
| − | | Reference = <ref>{{ | + | | Reference = <ref name="G&E">{{Greenwood&Earnshaw1st|pages=651–55}}.</ref> |
| − | | DeltaHf = | + | | DeltaHf = −276 kJ mol<sup>−1</sup> |
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| Section8 = {{Chembox Related | | Section8 = {{Chembox Related | ||
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| − | '''Bismuth bromide''', BiBr<sub>3</sub>, is the only well-characterized [[bromide]] of [[bismuth]]. It | + | '''Bismuth bromide''', BiBr<sub>3</sub>, is the only well-characterized [[bromide]] of [[bismuth]]. It has a number of specialist uses.<ref name="Kirk-Othmer">{{Kirk-Othmer | first1 = S. D. | last1 = Ukeles | first2 = M. | last2 = Freiberg | contribution = Bromine, Inorganic Compounds | doi = 10.1002/0471238961.021815131001031 | year = 2002}}.</ref> |
==Notes and references== | ==Notes and references== | ||
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==External links== | ==External links== | ||
| − | {{wikipedia|Bismuth | + | {{wikipedia|Bismuth tribromide}} |
*[http://www.webelements.com/compounds/bismuth/bismuth_tribromide.html WebElements] | *[http://www.webelements.com/compounds/bismuth/bismuth_tribromide.html WebElements] | ||
*{{UKPID|49|name=Bismuth}} | *{{UKPID|49|name=Bismuth}} | ||
Revision as of 15:21, 8 January 2011
| Bismuth bromide | |
|---|---|
| Other names | Bismuth(III) bromide Bismuth tribromide |
| Identifiers | |
| InChI | InChI=1/Be.2BrH/h;2*1H/q+2;;/p-2 |
| InChIKey | PBKYCFJFZMEFRS-NUQVWONBAJ |
| Standard InChI | InChI=1S/Be.2BrH/h;2*1H/q+2;;/p-2 |
| Standard InChIKey | PBKYCFJFZMEFRS-UHFFFAOYSA-L |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties[1] | |
| Chemical formula | BiBr3 |
| Molar mass | 168.82 g mol−1 |
| Appearance | off-white solid |
| Density | 5.72 g cm−3 |
| Melting point |
218 °C |
| Boiling point |
453 °C |
| Solubility in water | hydrolyzes |
| Thermochemistry[2] | |
| Std enthalpy of formation ΔfH |
−276 kJ mol−1 |
| Related compounds | |
| Other anions | Bismuth(III) fluoride Bismuth chloride Bismuth iodide |
| Other cations | Nitrogen tribromide Phosphorus tribromide Arsenic tribromide Antimony tribromide |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Bismuth bromide, BiBr3, is the only well-characterized bromide of bismuth. It has a number of specialist uses.[3]
Notes and references
Notes
References
- ↑ CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-82. ISBN 0-8493-0462-8.
- ↑ Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 651–55. ISBN 0-08-022057-6.
- ↑ Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
Further reading
- Aizawa, Hideyuki; Kuroda, Akio; Minaga, Masahiro, et al. (Toray Ind.) シクロヘキセンの製造方法 (Cyclohexene production method). JP Patent 51011736, published 30 January 1976.
- Joshi, Ashok V.; Sholette, William P. (Rat-O-Vac Corp) High energy density solid state cell. US Patent 4288505, published 8 September 1981.
- Smid, J. Makromol. Chem. Rapid Commun. 1987, 8, 543.
- Boyer, Bernard; Keramane, El-Mehdi; Roque, Jean-Pierre; Pavia, André A. BiBr3, an efficient catalyst for the benzylation of alcohols: 2-phenyl-2-propyl, a new benzyl-type protecting group. Tetrahedron Lett. 2000, 41 (16), 2891–94. DOI: 10.1016/S0040-4039(00)00304-X.
- Bajwa, Joginder S.; Jiang, Xinglong; Slade, Joel; Prasad, Kapa; Repič, Oljan; Blacklock, Thomas J. In-situ generation of Et3SiBr from BiBr3 and Et3SiH and its use in preparation of dialkyl ethers. Tetrahedron Letters 2002, 43 (38), 6709–13. DOI: 10.1016/S0040-4039(02)01532-0.
External links
 |
See also the corresponding article on Wikipedia. |
- WebElements
- Bismuth: UK Poison Information Document
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