Difference between revisions of "Thorium"
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Thorium was identified as a new element in 1828, and named after Thor, the Norse god of strength. Its chemistry resembles that of [[zirconium]] and [[hafnium]], with a preponderance of the +4 [[oxidation state]], and [[periodic table]]s from before the Second World War often placed thorium as a [[transition metal]]. | Thorium was identified as a new element in 1828, and named after Thor, the Norse god of strength. Its chemistry resembles that of [[zirconium]] and [[hafnium]], with a preponderance of the +4 [[oxidation state]], and [[periodic table]]s from before the Second World War often placed thorium as a [[transition metal]]. | ||
| − | ==Discovery== | + | ==Discovery and history== |
| − | Thorium was first identified in a sample of a new mineral (now called [[thorite]]) from the island of | + | Thorium was first identified in a sample of a new mineral (now called [[thorite]]) from the island of Løvøy in Vestfold, Norway. The sample was collected by the Lutheran pastor and amateur mineralogist Hans Morten Thrane Esmark; unable to identify it, he sent it to Christiana (modern-day Oslo) where his father Jens Esmark was professor of mineralogy and geology at the university. When Esmark Sr. had no more success than his son, he passed the sample on to the reknowned Swedish chemist [[Jöns Jacob Berzelius]], who correctly ascertained that the mineral contained a new chemical element.<ref>{{citation | first = J. J. | last = Berzelius | authorlink = Jöns Jacob Berzelius | title = Ueber den Thorit, ein neues Mineral, und eine darin enthaltene neue Erde, die Thorerde | journal = Ann. Phys. Chem. | year = 1829 | volume = 91 | issue = 4 | pages = 633–34 | doi = 10.1002/andp.18290910412}}.</ref><ref>{{citation | last = Berzelius | first = J. J. | authorlink = Jöns Jacob Berzelius | year = 1829 | title = Undersökning af ett nytt mineral (Thorit), som innehåller en förut obekant jord | journal = K. Sven. Vetenskapsakad. Handl. | volume = 9 | pages = 1–30}}; {{citation | title = Untersuchung eines neuen Minerals und einer darin enthaltenen zuvor unbekannten Erde | journal = Ann. Phys. Chem. | year = 1829 | volume = 92 | issue = 7 | pages = 385–415 | doi = 10.1002/andp.18290920702}}.</ref> The name predates the discovery of the element: in 1815, Berzelius had misidentified a sample of [[xenotime]] ([[yttrium phosphate]]) from the Falun mine in central Sweden as a new mineral containing a new element, and had chosen the names thorite and thorium.<ref>{{citation | last1 = Weeks | first1 = Mary Elvira | year = 1968 | title = Discovery of the Elements | edition = 7th | location = Easton, Penn. | page = 149}}.</ref> |
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| + | Thorium remained something of a curiosity until the invention of the incandescent gas mantle in 1885 by C. Auer von Welsbach. | ||
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| + | ==Occurance and extraction== | ||
==Notes and references== | ==Notes and references== | ||
Revision as of 19:58, 9 January 2011
Thorium (symbol: Th) is a member of the actinoid series of chemical elements. Although all isotopes of thorium are unstable, thorium-232 has a sufficiently long half-life (14 billion years) that a substantial amount of primordial thorium has survived since the formation of the Solar System. The natural material is only very slightly radioactive, and thorium and its compounds have a number of commercial uses, although some precautions must be taken over its decay products.
Thorium was identified as a new element in 1828, and named after Thor, the Norse god of strength. Its chemistry resembles that of zirconium and hafnium, with a preponderance of the +4 oxidation state, and periodic tables from before the Second World War often placed thorium as a transition metal.
Contents
Discovery and history
Thorium was first identified in a sample of a new mineral (now called thorite) from the island of Løvøy in Vestfold, Norway. The sample was collected by the Lutheran pastor and amateur mineralogist Hans Morten Thrane Esmark; unable to identify it, he sent it to Christiana (modern-day Oslo) where his father Jens Esmark was professor of mineralogy and geology at the university. When Esmark Sr. had no more success than his son, he passed the sample on to the reknowned Swedish chemist Jöns Jacob Berzelius, who correctly ascertained that the mineral contained a new chemical element.[1][2] The name predates the discovery of the element: in 1815, Berzelius had misidentified a sample of xenotime (yttrium phosphate) from the Falun mine in central Sweden as a new mineral containing a new element, and had chosen the names thorite and thorium.[3]
Thorium remained something of a curiosity until the invention of the incandescent gas mantle in 1885 by C. Auer von Welsbach.
Occurance and extraction
Notes and references
Notes
References
- ↑ Berzelius, J. J. Ueber den Thorit, ein neues Mineral, und eine darin enthaltene neue Erde, die Thorerde. Ann. Phys. Chem. 1829, 91 (4), 633–34. DOI: 10.1002/andp.18290910412.
- ↑ Berzelius, J. J. Undersökning af ett nytt mineral (Thorit), som innehåller en förut obekant jord. K. Sven. Vetenskapsakad. Handl. 1829, 9, 1–30; Untersuchung eines neuen Minerals und einer darin enthaltenen zuvor unbekannten Erde. Ann. Phys. Chem. 1829, 92 (7), 385–415. DOI: 10.1002/andp.18290920702.
- ↑ Weeks, Mary Elvira Discovery of the Elements, 7th ed.; Easton, Penn., 1968; p 149.
Further reading
- Wickleder, Mathias S.; Fourest, Blandine; Dorhout, Peter K. Thorium. In The Chemistry of the Actinide and Transactinide Elements, 3rd ed.; Morss, Lester R.; Edelstein, Norman M.; Fuger, Jean, Eds.; Springer: Dordrecht, the Netherlands, 2006; Vol. 1, Chapter 3, pp 52–160. doi:10.1007/1-4020-3598-5_3, <http://radchem.nevada.edu/classes/rdch710/files/thorium.pdf>.
External links
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See also the corresponding article on Wikipedia. |
