Difference between revisions of "File:Synthesis of Sceptrin.png"

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(This shows the main steps of the synthesis of sceptrin I, the creator of this image, do hereby declare it public domain)
 
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This shows the main steps of the synthesis of sceptrin
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{{Fileinfo
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| description = Part of [[Birman's synthesis of sceptrin]].
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| date = 2007-05-09
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| source = self-drawn
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| author = [[User:Fayettmr190]]
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| permission = released into the public domain by the author
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}}
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{{PD-author}}
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{{Substance identification
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| name = dimethyl (1S,2R,3R,4R)-3,4-bis(chloromethyl)cyclobutane-1,2-dicar​boxylate
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| InChI = 1/C10H14Cl2O4/c1-15-9(13)7-5(3-11)6(4-12)8(7)10(14)16-2/h5-​8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
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| StdInChI = 1S/C10H14Cl2O4/c1-15-9(13)7-5(3-11)6(4-12)8(7)10(14)16-2/h5​-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
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| InChIKey = WWRBIWFKAUTWEY-DKXJUACHBO
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| StdInChIKey = WWRBIWFKAUTWEY-DKXJUACHSA-N
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|  InChI_ref = [http://www.chemspider.com/9440675 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = dimethyl (1R,2S,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarb​oxylate
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| InChI = 1/C10H14N6O4/c1-19-9(17)7-5(3-13-15-11)6(4-14-16-12)8(7)10(​18)20-2/h5-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
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| StdInChI = 1S/C10H14N6O4/c1-19-9(17)7-5(3-13-15-11)6(4-14-16-12)8(7)10​(18)20-2/h5-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
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| InChIKey = FLHIKXZHCPXLOE-DKXJUACHBT
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| StdInChIKey = FLHIKXZHCPXLOE-DKXJUACHSA-N
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|  InChI_ref = [http://www.chemspider.com/9418055 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (1R,2R,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarboxylic ac​id
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| InChI = 1/C8H10N6O4/c9-13-11-1-3-4(2-12-14-10)6(8(17)18)5(3)7(15)16​/h3-6H,1-2H2,(H,15,16)(H,17,18)/t3-,4-,5+,6+/m0/s1
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| StdInChI = 1S/C8H10N6O4/c9-13-11-1-3-4(2-12-14-10)6(8(17)18)5(3)7(15)1​6/h3-6H,1-2H2,(H,15,16)(H,17,18)/t3-,4-,5+,6+/m0/s1
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| InChIKey = HNDASUZSROMZFI-UNTFVMJOBA
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| StdInChIKey = HNDASUZSROMZFI-UNTFVMJOSA-N
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|  InChI_ref = [http://www.chemspider.com/9463245 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (1R,2R,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarbonyl dichloride
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| InChI = 1/C8H8Cl2N6O2/c9-7(17)5-3(1-13-15-11)4(2-14-16-12)6(5)8(10)18/h3-6,11-12H,1-2H2/t3-,4-,5-,6+/m0/s1
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| StdInChI =
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| InChIKey =
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| StdInChIKey =
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|  InChI_ref =
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = 1-[(1R,2S,3S,4R)-2,3-bis(azidomethyl)-4-(2-bromoacetyl)cyclobutyl​]-2-bromo-ethanone
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| InChI = 1/C10H12Br2N6O2/c11-1-7(19)9-5(3-15-17-13)6(4-16-18-14)10(9​)8(20)2-12/h5-6,9-10H,1-4H2/t5-,6-,9-,10-/m0/s1
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| StdInChI = 1S/C10H12Br2N6O2/c11-1-7(19)9-5(3-15-17-13)6(4-16-18-14)10(​9)8(20)2-12/h5-6,9-10H,1-4H2/t5-,6-,9-,10-/m0/s1
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| InChIKey = XJFCGEJQHCWVMJ-XYMMMQBSBX
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| StdInChIKey = XJFCGEJQHCWVMJ-XYMMMQBSSA-N
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|  InChI_ref = [http://www.chemspider.com/9352363 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = tert-butyl N-[4-[(1R,2S,3S,4R)-2,3-bis(azidomethyl)-4-[2-(tert-bu​ toxycarbonylamino)-3H-imidazol-4-yl]cyclobutyl]-3H-imidazol-2-yl]​ carbamate
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| InChI = 1/C22H32N12O4/c1-21(2,3)37-19(35)31-17-25-9-13(29-17)15-11( ​7-27-33-23)12(8-28-34-24)16(15)14-10-26-18(30-14)32-20(36)38-22(4​ ,5)6/h9-12,15-16H,7-8H2,1-6H3,(H2,25,29,31,35)(H2,26,30,32,36)/t1​ 1-,12-,15-,16-/m0/s1
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| StdInChI = 1S/C22H32N12O4/c1-21(2,3)37-19(35)31-17-25-9-13(29-17)15-11 ​(7-27-33-23)12(8-28-34-24)16(15)14-10-26-18(30-14)32-20(36)38-22(​ 4,5)6/h9-12,15-16H,7-8H2,1-6H3,(H2,25,29,31,35)(H2,26,30,32,36)/t​ 11-,12-,15-,16-/m0/s1
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| InChIKey = XHJJTNJSLTWPRI-APYUEPQZBY
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| StdInChIKey = XHJJTNJSLTWPRI-APYUEPQZSA-N
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|  InChI_ref = [http://www.chemspider.com/9584839 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
  
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I, the creator of this image, do hereby declare it public domain
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[[Category:Total syntheses]]

Revision as of 05:05, 18 August 2009

Description Part of Birman's synthesis of sceptrin.
Date 2007-05-09
Source self-drawn
Author User:Fayettmr190
Permission released into the public domain by the author
No copyright 200px.png This file has been (or is hereby) released into the public domain by its author. This applies worldwide.
In case this is not legally possible, the author has granted (or grants hereby) anyone the right to use this work for any purpose, without any conditions, unless such conditions are required by law.
Substance identification
This file contains an image or representation of, or data relating to, dimethyl (1S,2R,3R,4R)-3,4-bis(chloromethyl)cyclobutane-1,2-dicar​boxylate.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C10H14Cl2O4/c1-15-9(13)7-5(3-11)6(4-12)8(7)10(14)16-2/h5-​8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
 InChI=1S/C10H14Cl2O4/c1-15-9(13)7-5(3-11)6(4-12)8(7)10(14)16-2/h5​-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
InChIKeys: WWRBIWFKAUTWEY-DKXJUACHBO, WWRBIWFKAUTWEY-DKXJUACHSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, dimethyl (1R,2S,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarb​oxylate.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C10H14N6O4/c1-19-9(17)7-5(3-13-15-11)6(4-14-16-12)8(7)10(​18)20-2/h5-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
 InChI=1S/C10H14N6O4/c1-19-9(17)7-5(3-13-15-11)6(4-14-16-12)8(7)10​(18)20-2/h5-8H,3-4H2,1-2H3/t5-,6-,7-,8+/m0/s1
InChIKeys: FLHIKXZHCPXLOE-DKXJUACHBT, FLHIKXZHCPXLOE-DKXJUACHSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (1R,2R,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarboxylic ac​id.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C8H10N6O4/c9-13-11-1-3-4(2-12-14-10)6(8(17)18)5(3)7(15)16​/h3-6H,1-2H2,(H,15,16)(H,17,18)/t3-,4-,5+,6+/m0/s1
 InChI=1S/C8H10N6O4/c9-13-11-1-3-4(2-12-14-10)6(8(17)18)5(3)7(15)1​6/h3-6H,1-2H2,(H,15,16)(H,17,18)/t3-,4-,5+,6+/m0/s1
InChIKeys: HNDASUZSROMZFI-UNTFVMJOBA, HNDASUZSROMZFI-UNTFVMJOSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (1R,2R,3S,4S)-3,4-bis(azidomethyl)cyclobutane-1,2-dicarbonyl dichloride.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C8H8Cl2N6O2/c9-7(17)5-3(1-13-15-11)4(2-14-16-12)6(5)8(10)18/h3-6,11-12H,1-2H2/t3-,4-,5-,6+/m0/s1
Substance identification
This file contains an image or representation of, or data relating to, 1-[(1R,2S,3S,4R)-2,3-bis(azidomethyl)-4-(2-bromoacetyl)cyclobutyl​]-2-bromo-ethanone.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C10H12Br2N6O2/c11-1-7(19)9-5(3-15-17-13)6(4-16-18-14)10(9​)8(20)2-12/h5-6,9-10H,1-4H2/t5-,6-,9-,10-/m0/s1
 InChI=1S/C10H12Br2N6O2/c11-1-7(19)9-5(3-15-17-13)6(4-16-18-14)10(​9)8(20)2-12/h5-6,9-10H,1-4H2/t5-,6-,9-,10-/m0/s1
InChIKeys: XJFCGEJQHCWVMJ-XYMMMQBSBX, XJFCGEJQHCWVMJ-XYMMMQBSSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, tert-butyl N-[4-[(1R,2S,3S,4R)-2,3-bis(azidomethyl)-4-[2-(tert-bu​ toxycarbonylamino)-3H-imidazol-4-yl]cyclobutyl]-3H-imidazol-2-yl]​ carbamate.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C22H32N12O4/c1-21(2,3)37-19(35)31-17-25-9-13(29-17)15-11( ​7-27-33-23)12(8-28-34-24)16(15)14-10-26-18(30-14)32-20(36)38-22(4​ ,5)6/h9-12,15-16H,7-8H2,1-6H3,(H2,25,29,31,35)(H2,26,30,32,36)/t1​ 1-,12-,15-,16-/m0/s1
 InChI=1S/C22H32N12O4/c1-21(2,3)37-19(35)31-17-25-9-13(29-17)15-11 ​(7-27-33-23)12(8-28-34-24)16(15)14-10-26-18(30-14)32-20(36)38-22(​ 4,5)6/h9-12,15-16H,7-8H2,1-6H3,(H2,25,29,31,35)(H2,26,30,32,36)/t​ 11-,12-,15-,16-/m0/s1
InChIKeys: XHJJTNJSLTWPRI-APYUEPQZBY, XHJJTNJSLTWPRI-APYUEPQZSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider

File history

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Date/TimeThumbnailDimensionsUserComment
current11:03, 9 May 2007Thumbnail for version as of 11:03, 9 May 20072,123 × 962 (46 KB)Fayettmr190 (talk | contribs)This shows the main steps of the synthesis of sceptrin I, the creator of this image, do hereby declare it public domain
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