Difference between revisions of "File:Digitoxigeninfinalsynthesis.png"

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| description = Part of [[Nakada's synthesis of digitoxigenin]]
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| date =
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| source =
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| author =
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| permission =
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}}
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{{Substance identification
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| name = (6''R'',7''R'')-6-(2-bromoethyl)-7-(furan-3-yl)-6-methyl-1,4-dioxaspiro[4.4]nonane
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| InChI = 1/C14H19BrO3/c1-13(5-6-15)12(11-3-7-16-10-11)2-4-14(13)17-8​-9-18-14/h3,7,10,12H,2,4-6,8-9H2,1H3/t12-,13-/m1/s1
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| StdInChI = 1S/C14H19BrO3/c1-13(5-6-15)12(11-3-7-16-10-11)2-4-14(13)17-​8-9-18-14/h3,7,10,12H,2,4-6,8-9H2,1H3/t12-,13-/m1/s1
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| InChIKey = XXNCPTRRNYOWOR-CHWSQXEVBS
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| StdInChIKey = XXNCPTRRNYOWOR-CHWSQXEVSA-N
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|  InChI_ref = [http://www.chemspider.com/17229170 ChemSpider]
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = (4a''S'',7''S'',8a''S'')-7-[''tert''-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalen-2-one
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| InChI = 1/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-14 ​-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,1​ 6,18-20H2,1-4H3/t21-,23+,27+/m1/s1
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| StdInChI = 1S/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-1 ​4-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,​ 16,18-20H2,1-4H3/t21-,23+,27+/m1/s1
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| InChIKey = YGGDIROWPHRHNN-ZYVVXELTBM
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| StdInChIKey = YGGDIROWPHRHNN-ZYVVXELTSA-N
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|  InChI_ref = [http://www.chemspider.com/17229170 ChemSpider]<br/>'''Note''': InChIs and name are for the enantiomer with specified (''S'')-stereochemistry at carbon-7 (the one used into the digitoxigenin sysnthesis)
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name =
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| InChI =
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| StdInChI =
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| InChIKey =
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| StdInChIKey =
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|  InChI_ref =
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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}}
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{{Substance identification
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| name =
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| InChI =
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| StdInChI =
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| InChIKey =
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| StdInChIKey =
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|  InChI_ref =
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name =
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| InChI =
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| StdInChI =
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| InChIKey =
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| StdInChIKey =
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|  InChI_ref =
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| CASNo =
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|  CASNo_ref =
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| ECNo =
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|  ECNo_ref =
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}}
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{{Substance identification
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| name = digitoxigenin
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| InChI = 1/C23H34O4/c1-21-8-5-16(24)12-15(21)3-4-19-18(21)6-9-22(2)1 ​7(7-10-23(19,22)26)14-11-20(25)27-13-14/h11,15-19,24,26H,3-10,12-​ 13H2,1-2H3/t15-,16+,17-,18+,19-,21+,22-,23+/m1/s1
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| StdInChI = 1S/C23H34O4/c1-21-8-5-16(24)12-15(21)3-4-19-18(21)6-9-22(2) ​17(7-10-23(19,22)26)14-11-20(25)27-13-14/h11,15-19,24,26H,3-10,12​ -13H2,1-2H3/t15-,16+,17-,18+,19-,21+,22-,23+/m1/s1
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| InChIKey = XZTUSOXSLKTKJQ-CESUGQOBBG
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| StdInChIKey = XZTUSOXSLKTKJQ-CESUGQOBSA-N
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|  InChI_ref = [http://www.chemspider.com/3571902 ChemSpider]
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| CASNo = 143-62-4
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|  CASNo_ref = CAS Common Chemistry
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| ECNo = 205-603-4
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|  ECNo_ref = ESIS
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}}
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[[Category:Total syntheses]]

Revision as of 15:25, 16 August 2009

Exclamation red.png This file is lacking valid copyright license information. Please add this information, preferably in the form of a license tag, as soon as possible or the file may be deleted. See WikiChem:Copyrights for more details.
Description Part of Nakada's synthesis of digitoxigenin
Date
Source
Author
Permission
Substance identification
This file contains an image or representation of, or data relating to, (6R,7R)-6-(2-bromoethyl)-7-(furan-3-yl)-6-methyl-1,4-dioxaspiro[4.4]nonane.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C14H19BrO3/c1-13(5-6-15)12(11-3-7-16-10-11)2-4-14(13)17-8​-9-18-14/h3,7,10,12H,2,4-6,8-9H2,1H3/t12-,13-/m1/s1
 InChI=1S/C14H19BrO3/c1-13(5-6-15)12(11-3-7-16-10-11)2-4-14(13)17-​8-9-18-14/h3,7,10,12H,2,4-6,8-9H2,1H3/t12-,13-/m1/s1
InChIKeys: XXNCPTRRNYOWOR-CHWSQXEVBS, XXNCPTRRNYOWOR-CHWSQXEVSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Substance identification
This file contains an image or representation of, or data relating to, (4aS,7S,8aS)-7-[tert-butyl(diphenyl)silyl]oxy-4a-methyl-1,5,6,7,8,8a-hexahydronaphthalen-2-one.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-14 ​-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,1​ 6,18-20H2,1-4H3/t21-,23+,27+/m1/s1
 InChI=1S/C27H34O2Si/c1-26(2,3)30(24-11-7-5-8-12-24,25-13-9-6-10-1 ​4-25)29-23-16-18-27(4)17-15-22(28)19-21(27)20-23/h5-15,17,21,23H,​ 16,18-20H2,1-4H3/t21-,23+,27+/m1/s1
InChIKeys: YGGDIROWPHRHNN-ZYVVXELTBM, YGGDIROWPHRHNN-ZYVVXELTSA-N
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
Note: InChIs and name are for the enantiomer with specified (S)-stereochemistry at carbon-7 (the one used into the digitoxigenin sysnthesis)
Substance identification
This file contains an image or representation of, or data relating to, '.
Substance identification
This file contains an image or representation of, or data relating to, '.
Substance identification
This file contains an image or representation of, or data relating to, '.
Substance identification
This file contains an image or representation of, or data relating to, digitoxigenin.
Error creating thumbnail: Unable to save thumbnail to destination
 International Chemical Identifiers (InChI)
 InChI=1/C23H34O4/c1-21-8-5-16(24)12-15(21)3-4-19-18(21)6-9-22(2)1 ​7(7-10-23(19,22)26)14-11-20(25)27-13-14/h11,15-19,24,26H,3-10,12-​ 13H2,1-2H3/t15-,16+,17-,18+,19-,21+,22-,23+/m1/s1
 InChI=1S/C23H34O4/c1-21-8-5-16(24)12-15(21)3-4-19-18(21)6-9-22(2) ​17(7-10-23(19,22)26)14-11-20(25)27-13-14/h11,15-19,24,26H,3-10,12​ -13H2,1-2H3/t15-,16+,17-,18+,19-,21+,22-,23+/m1/s1
InChIKeys: XZTUSOXSLKTKJQ-CESUGQOBBG, XZTUSOXSLKTKJQ-CESUGQOBSA-N
CAS registry number: [143-62-4]
EC number: 205-603-4
Green tick.png These identifiers have been verified against the following sources:
InChI: ChemSpider
CAS registry number: CAS Common Chemistry
EC number: ESIS

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