Barium bromite
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| Barium bromite | |
|---|---|
| IUPAC name | Barium bromite |
| Other names | Barium bromate(III) |
| Identifiers | |
| InChI | InChI=1/Ba.2BrO2/c;2*2-1-3/q+2;2*-1 |
| Standard InChI | InChI=1S/Ba.2BrHO2/c;2*2-1-3/h;2*(H,2,3)/q+2;;/p-2 |
| Standard InChIKey | PGLMIJFEJJTLFA-UHFFFAOYSA-L |
| CAS number | [] |
| Properties | |
| Chemical formula | Ba(BrO2)2 |
| Molar mass | 361.13 g mol−1 |
| Related compounds | |
| Other anions | Barium chlorite |
| Other cations | Strontium bromite |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Barium bromite, Ba(BrO2)2, is formally the barium salt of bromous acid. It was the first bromite to be isolated, as the monohydrate,[1] which is formed by the controlled disproportionation of barium hypobromite at pH 11–12 and 0 °C.[2][3][4] The anhydrous salt can be prepared by heating barium bromate to 250 °C in vacuo.[5]
Notes and references
Notes
References
- ↑ Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; p 1009. ISBN 0-08-022057-6.
- ↑ Kircher, R.; Periat, R. Preparation du bromite de baryum cristallisé. Ind. Chim. Belge, Suppl. 1 1959, 877.
- ↑ Kircher, René; Periat, Robert (Société d'Etudes Chimiques pour l'Industrie et l'Agriculture) Verfahren zur Herstellung von Bariumbromit durch Disproportionierung von Bariumhypobromit. DE Patent 1076096, published 25 February 1960.
- ↑ Massagli, A.; Indelli, A.; Pergola, F. Kinetic investigation of the decomposition of bromite. Inorg. Chim. Acta 1970, 4 (4), 593–96. DOI: 10.1016/S0020-1693(00)93357-7.
- ↑ Downs, A. J.; Adams, C. J. In Comprehensive Inorganic Chemistry; Bailar, J. C., Jr.; Emeleus, H. J.; Nyholm, R., et al., Eds.; Pergamon: Oxford, 1973; Vol. 2, pp 1419–20.
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