Lithium bromite
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| Lithium bromite | |
|---|---|
| IUPAC name | Lithium bromite |
| Other names | Lithium bromate(III) |
| Identifiers | |
| Standard InChI | InChI=1S/BrHO2.Li/c2-1-3;/h(H,2,3);/q;+1/p-1 |
| Standard InChIKey | VLRXBEHPKIJLJR-UHFFFAOYSA-M |
| CAS number | [] |
| Properties | |
| Chemical formula | LiBrO2 |
| Molar mass | 118.84 g mol−1 |
| Related compounds | |
| Other anions | Lithium chlorite |
| Other cations | Sodium bromite Potassium bromite |
| Other compounds | Lithium bromide Lithium hypobromite Lithium bromate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Lithium bromite, LiBrO2, is formally the lithium salt of bromous acid. It is prepared by the controlled disproportionation of lithium hypobromite at pH 11–12 and 0 °C.[1][2] The anhydrous salt can be prepared by heating lithium bromate with lithium bromide at 190 °C.[3]
- 2 LiBrO3 + LiBr → 3 LiBrO2
Notes and references
Notes
References
- ↑ Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
- ↑ Meybeck, Jean; Kircher, René; Breiss, Jacqueline (Société d'Etudes Chimiques pour l'Industrie et l'Agriculture) Procédé d'obtention de dérévés oxygénés du brome, à l'état solide, et produits industriels en résultant. FR Patent 1216216, published 22 April 1960; Alkaline Earth Bromites. US Patent 3178262.
- ↑ Downs, A. J.; Adams, C. J. In Comprehensive Inorganic Chemistry; Bailar, J. C., Jr.; Emeleus, H. J.; Nyholm, R., et al., Eds.; Pergamon: Oxford, 1973; Vol. 2, pp 1419–20.
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