Aluminium phosphate
| Aluminium phosphate | |
|---|---|
| |
| Other names | Aluminium monophosphate Phosphoric acid, aluminum salt (1:1) |
| Identifiers | |
| InChI | InChI=1/Al.H3O4P/c;1-5(2,3)4/h;(H3,1,2,3,4)/q+3;/p-3/rAlO4P/c2-6-3-1(4-6)5-6 |
| InChIKey | ILRRQNADMUWWFW-ITXURHEJAW |
| CAS number | [] |
| RTECS | TB6450000 |
| ChemSpider | |
| PubChem | |
| SMILES | |
| Properties | |
| Chemical formula | AlPO4 |
| Molar mass | 121.9529 g/mol |
| Appearance | white, crystalline powder |
| Density | 2.566 g/cm3, solid |
| Melting point |
1800 °C |
| Boiling point |
decomposes |
| Solubility in water | insoluble |
| Solubility | very slightly soluble in HCl and HNO3 |
| Refractive index (nD) | 1.546 [1] |
| Hazards | |
| EU classification | Xi |
| R-phrases | Template:R36/37/38 |
| S-phrases | Template:S26 |
| NFPA 704 |
 |
| LD50 | 4640mg/kg (rat, oral) > 4640 mg/kg (rabbit, dermal) |
| Template:Tick(what is this?) (verify) Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Aluminium phosphate (AlPO4) is a chemical compound. It is used in cake mixes and in some baking powders as a leavening agent to help baked goods rise. Medicinally it is used as adsorbent for toxoid.
It is also used industrially as a high-temperature dehydrating agent. When heated to decomposition, aluminium phosphate decomposes into aluminium oxide and phosphorus pentoxide, the latter of which is very effective at absorbing water.[2][3] Phosphorus pentoxide may be useful in a number of applications including the production of ketene from acetic acid, although this process is rather dangerous and may yield a significant amount of byproducts.[4]
Occurrence
Although it is unstable to heat, in geologically stable regions like Australia and Southern Africa, alumiunium phosphate is generally the most common form of phosphorus in soils, as it forms when phosphate in rainwater reacts with dissolved aluminium in the soil. Although it is not as insoluble as many other components of soils in those regions, aluminium phosphate can form exceedingly insoluble double salts known as taranakites with many essential elements for plant growth that are normally highly soluble in water, such as potassium and nitrogen.
In coastal areas of South Africa and Namibia, the combination of exceedingly old soils and a high input of phosphate from very fertile oceans due to the Benguela Current causes aluminium phosphate to accumulate to form a concentrated mineral, known as aluminium phosphate rock. Only in recent years has there been any interest in the mining of these considerable deposits as a source of phosphorus for agriculture, but there could be considerable economic value if low-cost treatment becomes possible.
The mineral form of aluminium phosphate, berlinite, is rarely found in the nature. It possess quartz-like structure, which makes these 2 minerals often hard to distinguish by standard laboratory methods (like Powder X-Ray Diffraction)
References
- ↑ Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398
- ↑ http://www.spipharma.com/downloads/Products/AntacidActives/Specialty_Products/AlPhosphateMSDS.pdf, Aluminum phosphate MSDS, SPI Pharma
- ↑ http://www.nithyasrichemicals.com/aluminium-based-products.html, Aluminium Based Products at Nithyasri Chemicals]
- ↑ http://www.sciencemadness.org/talk/viewthread.php?tid=12694, Sciencemadness thread "Aluminum phosphate decomposition"
- ↑ Ibid
External links
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