Sodium manganite

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Sodium manganite, NaMnO2, is a mixed oxide of sodium and manganese(III). It adopts a distorted halite (NaCl) structure in its two crystalline forms, with the MnO6 octahedra being distorted by the Jahn–Teller effect of the d4 Mn3+ cation.[1][2]

References

  1. ↑ Jansen, M.; Hoppe, R. Zur Kenntnis der NaCl-Strukturfamilie Die Kristallstruktur von NaMnO2. Z. Anorg. Allg. Chem., 399 (2), 163–69. DOI: 10.1002/zaac.19733990204.
  2. ↑ Hoppe, R.; Brachtel, G.; Jansen, M. Zur Kenntnis der Oxomanganate(III): Über LiMnO2 und β-NaMnO2. Z. Anorg. Allg. Chem., 417 (1), 1–10. DOI: 10.1002/zaac.19754170102.
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