Caesium hexatitanate

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Caesium hexatitanate
IUPAC name caesium oxide—titanium dioxide (1/6)
Identifiers
InChI InChI=1/2Cs.13O.6Ti/q2*+1;13*-2;6*+4
CAS number [98084-25-4]
Properties
Chemical formula Cs2Ti6O13
Molar mass 761.01 g mol−1
Appearance white solid
Structure
Coordination geometry Octahedral (Ti4+)
Hazards
EU index number not listed
Related compounds
Other anions Caesium pentatitanate
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Caesium hexatitanate, Cs2Ti6O13, is a mixed oxide of caesium and titanium. It is formed by heating a mixture of caesium carbonate and titanium dioxide at 850–1200 °C, and has a layer structure of edge-sharing TiO6 octahedra with Cs+ cations between the layers.[1]

Notes and references

Notes

References

  1. Grey, I. E.; Madsen, I. C.; Watts, J. A.; Bursill, L. A.; Kwiatkowska, J. New cesium titanate layer structures. J. Solid State Chem. 1985, 58 (3), 350–56. DOI: 10.1016/0022-4596(85)90217-8.
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