Calcium hypobromite

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Calcium hypobromite
Other names Calcium bromate(I)
Identifiers
InChI InChI=1/2BrO.Ca/c2*1-2;/q2*-1;+2
InChIKey XVDWMONETMNKBK-UHFFFAOYAM
Standard InChI InChI=1S/2BrO.Ca/c2*1-2;/q2*-1;+2
Standard InChIKey XVDWMONETMNKBK-UHFFFAOYSA-N
ChemSpider 8031762
Properties
Chemical formula Ca(BrO)2
Molar mass 231.88 g mol−1
Related compounds
Other anions Calcium hypochlorite
Other cations Strontium hypobromite
Barium hypobromite
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Calcium bromide hypobromite
IUPAC name Calcium bromide — calcium hypobromite (1/1)
Identifiers
Standard InChI InChI=1S/2BrO.2BrH.2Ca/c2*1-2;;;;/h;;2*1H;;/q2*-1;;;2*+2/p-2
Standard InChIKey ZRZHMUOEPUZHKK-UHFFFAOYSA-L
CAS number [67530-61-4]
Properties
Chemical formula CaBr2·Ca(BrO)2O
Molar mass 431.77 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Calcium hypobromite, Ca(BrO)2, is the calcium salt of hypobromous acid. It can be prepared by the reaction of bromine with aqueous calcium hydroxide solution at 0 °C or lower.[1] The product of the reaction of bromine with solid calcium hydroxide is formulated as CaBr(BrO) or, equivalently, Ca(BrO)2·CaBr2.[2] It has long been known as a strong oxidizing and bleaching agent.[2]

Notes and references

Notes

References

  1. Cotton, F. Albert; Wilkinson, Geoffrey Advanced Inorganic Chemistry, 5th ed.; Wiley-Interscience: New York, 1988; pp 563–67. ISBN 0-471-84997-9.
  2. 2.0 2.1 Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
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