Perbromate
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| Perbromate | |
|---|---|
| Other names | Tetraoxidobromate(1−) |
| Identifiers | |
| InChI | InChI=1/BrHO4/c2-1(3,4)5/h(H,2,3,4,5)/p-1 |
| InChIKey | LLYCMZGLHLKPPU-REWHXWOFAT |
| Standard InChI | InChI=1S/BrHO4/c2-1(3,4)5/h(H,2,3,4,5)/p-1 |
| Standard InChIKey | LLYCMZGLHLKPPU-UHFFFAOYSA-M |
| CAS number | [] |
| ChemSpider | |
| Structure[1] | |
| Molecular geometry | r(Br–O) = 161 pm |
| Related compounds | |
| Other anions | Perchlorate Periodate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
A perbromate is a salt or ester of perbromic acid. Perbromates, including perbromic acid,[note 1] are the only well-characterized compounds of bromine in the +7 oxidation state.
Perbromates are thermodynamically more oxidizing than perchlorates or periodates, and eluded preparation for more than 100 years until 1968.[2][3] However, they are kinetically quite inert, especially in dilute solution.[3]
Notes and references
Notes
- ↑ Perbromic acid is fully dissociated in solution. By analogy with perchloric acid, the solid HBrO4·2H2O is expected to contain [(H2O)2H]+[BrO4]−.
References
- ↑ Levason, William; Ogden, J. Steven; Spicer, Mark D.; Young, Nigel A. Characterisation of the oxo-anions of bromine BrOx− (x = 1–4) by infrared, Raman, nuclear magnetic resonance, and bromine K-edge extended X-ray absorption fine structure techniques. J. Chem. Soc., Dalton Trans. 1990 (1), 349–53. DOI: 10.1039/DT9900000349.
- ↑ Appelman, Evan H. The Synthesis of perbromates. J. Am. Chem. Soc. 1968, 90 (7), 1900–1. DOI: 10.1021/ja01009a040.
- ↑ 3.0 3.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1020–22. ISBN 0-08-022057-6.
Further reading
- Appelman, E. H. Inorg. Chem. 1969, 8, 223.
- Johnson, G. K.; Smith, P. N.; Appelman, E. H.; Hubbard, W. N. Inorg. Chem. 1970, 9, 119.
- Klaening, V. K.; Olsen, K. J.; Appelman, E. H. J. Chem. Soc., Faraday Trans. 1 1975, 71, 473.
- Olsen, K. J.; Sehested, K.; Appelman, E. H. Chem. Phys. Lett. 1973, 19, 213.
- Baum, Kurt; Beard, Charles D.; Grakauskas, Vytautas Preparation of an alkyl perbromate. J. Am. Chem. Soc. 1975, 97 (2), 267–68. DOI: 10.1021/ja00835a005.
External links
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See also the corresponding article on Wikipedia. |
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