Lithium sulfate

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Lithium sulfate
IUPAC name Lithium sulfate
Identifiers
CAS number [10377-48-7],
10102-25-7 (monohydrate)
RTECS OJ6419000
PubChem 66320
Properties[1]
Chemical formula Li2SO4
Molar mass 109.94 g/mol
Appearance White crystalline solid, hygroscopic
Density 2.221 g/cm3 (anhydrous)
2.06 g/cm3 (monohydrate)
Melting point

859 °C

Boiling point

1377 °C

Solubility in water monohydrate:
34.9 g/100 mL (25 °C)
29.2 g/100 mL (100 °C)
Solubility insoluble in absolute ethanol, acetone and pyridine
Refractive index (nD) 1.465
Structure
Thermochemistry
Std enthalpy of formation ΔfHo298 -13.07 kJ/g
Specific heat capacity C 1.07 J/g K
Hazards
EU index number Not listed
NFPA 704
NFPA 704.png
 
 
 
 
Related compounds
Other cations Sodium sulfate
Potassium sulfate
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Lithium sulfate is a white inorganic salt with the formula Li2SO4. It is used to treat bipolar disorder (see lithium pharmacology). It is soluble in water, though it does not follow the usual trend of solubility versus temperature — its solubility in water decreases with increasing temperature. This property is shared with few inorganic compounds, such as the lanthanoid sulfates.

Lithium sulfate crystals, being piezoelectric, are also used in ultrasound-type non-destructive testing because they are very efficient sound generators. However they do suffer in this application because of their water solubility.

References

  1. Pradyot Patnaik. Handbook of Inorganic Chemicals. McGraw-Hill, 2002, ISBN 0070494398


Template:Bipolar disorder

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