Lithium manganite
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Lithium manganite | |
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IUPAC name | lithium manganese dioxide |
Properties | |
Chemical formula | LiMnO2 |
Molar mass | 93.878 g mol−1 |
Structure[1] | |
Crystal structure | Distorted halite (NaCl) |
Space group | Pmnm |
Lattice constant | a = 280(5) pm, b = 575(7) pm, c = 457(2) pm |
Coordination geometry | Distorted octahedral (Li+, Mn3+) Distorted octahedral (O2−) |
Related compounds | |
Other anions | Lithium manganate Lithium permanganate |
Other cations | Sodium manganite Potassium manganite |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Lithium manganite, LiMnO2, is a mixed oxide of lithium and manganese(III). It adopts a distorted halite (NaCl) structure in its two crystalline forms, with the MnO6 octahedra being distorted by the Jahn–Teller effect of the d4 Mn3+ cation.[1]
References
- ↑ 1.0 1.1 Hoppe, R.; Brachtel, G.; Jansen, M. Zur Kenntnis der Oxomanganate(III): Über LiMnO2 und β-NaMnO2. Z. Anorg. Allg. Chem., 417 (1), 1–10. DOI: 10.1002/zaac.19754170102.
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