Calcium hypobromite

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Calcium hypobromite
Other names Calcium bromate(I)
Identifiers
InChI InChI=1/2BrO.Ca/c2*1-2;/q2*-1;+2
InChIKey XVDWMONETMNKBK-UHFFFAOYAM
Standard InChI InChI=1S/2BrO.Ca/c2*1-2;/q2*-1;+2
Standard InChIKey XVDWMONETMNKBK-UHFFFAOYSA-N
ChemSpider 8031762
Properties
Chemical formula Ca(BrO)2
Molar mass 231.88 g mol−1
Related compounds
Other anions Calcium hypochlorite
Other cations Strontium hypobromite
Barium hypobromite
Other compounds Calcium bromide
Calcium bromite
Calcium bromate
Calcium perbromate
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Calcium bromide hypobromite
IUPAC name Calcium bromide — calcium hypobromite (1/1)
Identifiers
Standard InChI InChI=1S/2BrO.2BrH.2Ca/c2*1-2;;;;/h;;2*1H;;/q2*-1;;;2*+2/p-2
Standard InChIKey ZRZHMUOEPUZHKK-UHFFFAOYSA-L
CAS number [67530-61-4]
Properties
Chemical formula CaBr2·Ca(BrO)2
Molar mass 431.77 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Calcium hypobromite, Ca(BrO)2, is the calcium salt of hypobromous acid. It can be prepared by the reaction of bromine with aqueous calcium hydroxide solution at 0 °C or lower.[1] The product of the reaction of bromine with solid calcium hydroxide is formulated as CaBr(BrO) or, equivalently, Ca(BrO)2·CaBr2.[2] It has long been known as a strong oxidizing and bleaching agent.[2]

Notes and references

Notes

References

  1. Cotton, F. Albert; Wilkinson, Geoffrey Advanced Inorganic Chemistry, 5th ed.; Wiley-Interscience: New York, 1988; pp 563–67. ISBN 0-471-84997-9.
  2. 2.0 2.1 Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
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