Potassium aluminium sulfate

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Potassium aluminium sulfate dodecahydrate
Aluminium potassium sulfate
IUPAC name Aluminium potassium bis(sulfate) — water (1:12)
Other names Potassium alum
Potash alum
Alum
Kalinite
Identifiers
InChI InChI=1/Al.K.2H2O4S.12H2O/c;;2* 1-5(2,3)4;;;;;;;;;;;;/h;;2*(H2 ,1,2,3,4);12*1H2/q+3;+1;;;;;;;
;;;;;;;/p-4
InChIKey GNHOJBNSNUXZQA-XBHQNQODAI
Standard InChI InChI=1S/Al.K.2H2O4S.12H2O/c;;2 *1-5(2,3)4;;;;;;;;;;;;/h;;2*(H 2,1,2,3,4);12*1H2/q+3;+1;;;;;;
;;;;;;;;/p-4
Standard InChIKey GNHOJBNSNUXZQA-UHFFFAOYSA-J
CAS number [7784-24-9]
EC number 233-141-3
ChemSpider 56418
Properties[1]
Chemical formula KAl(SO4)2·12H2O
Molar mass 474.39 g/mol
Density 1.757 g/cm3 (20 °C)
Melting point

64.5 °C (−9H2O)
92.5 °C

Boiling point

200 °C dehydr.

Solubility in water 11.4 g/100 ml (20 °C)
Refractive index (nD) 1.454
Structure[2]
Crystal structure Cubic, cP96
Space group Pa3, No. 205
Lattice constant a = 1216.40(5) pm
Coordination geometry Octahedral (K+)
Octahedral (Al3+)
Hazards
EU index number not listed
Flash point non-flammable
Related compounds
Other cations Sodium aluminium sulfate
Ammonium aluminium sulfate
Potassium chromium(III) sulfate
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Potassium aluminium sulfate (anhydrous)
Aluminium potassium sulfate
IUPAC name Aluminium potassium bis(sulfate)
Identifiers
InChI InChI=1/Al.K.2H2O4S/c;;2*1-5(2,3)4/h;;2*(H2,1,2,3,4)/q+3;+1;;/p-4
InChIKey GRLPQNLYRHEGIJ-XBHQNQODAE
Standard InChI InChI=1S/Al.K.2H2O4S/c;;2*1-5(2,3)4/h;;2*(H2,1,2,3,4)/q+3;+1;;/p-​4
Standard InChIKey GRLPQNLYRHEGIJ-UHFFFAOYSA-J
CAS number [10043-67-1]
EC number 233-141-3
ChemSpider 23239
Properties
Chemical formula KAl(SO4)2
Molar mass 258.21 g/mol
Hazards[3]
EU index number not listed
GHS pictograms Acute Tox. 4 (oral); Skin Irrit. 2; Eye Irrit. 2Corr. Met. 1
GHS signal word WARNING
GHS hazard statements H302, H315, H319
GHS precautionary statements P234, P264, P270, P280, P301+312, P302+352, P305+351+338, P321, P330, P332+313, P337+313, P362, P390, P406
Flash point non-flammable
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Potassium aluminium sulfate, better known as potassium alum or potash alum, is the double sulfate of aluminium and potassium. Its chemical formula is KAl(SO4)2 and it is commonly found in its dodecahydrate form as KAl(SO4)2·12(H2O). The dodechydrate is sometimes commercialised as alum: this name is ambiguous in chemical nomenclature, as potassium aluminium sulfate is one of several alums (double sulfates of aluminium with a monovalent cation). It is commonly used in water purification, leather tanning, fireproof textiles, and baking powder. It also has uses as a deodorant, as an aftershave treatment and as acidity regulator in food (E522).

Characteristics

Potassium alum crystallizes in regular octahedra with flattened corners, and is very soluble in water. The solution reddens litmus and is an astringent. When heated to nearly a red heat it gives a porous, friable mass which is known as "burnt alum." It fuses at 92 °C in its own water of crystallization. "Neutral alum" is obtained by the addition of as much sodium carbonate to a solution of alum as will begin to cause the separation of alumina. Alum finds application as a mordant, in the preparation of lakes for sizing hand-made paper and in the clarifying of turbid liquids.

Mineral form and occurrence

The mineral form of potassium alum is officially known as alum-(K).[4] It is a naturally occurring sulfate mineral which typically occurs as encrustations on rocks in areas of weathering and oxidation of sulfide minerals and potassium-bearing minerals. [5] It has been reported at

Kalinite, a fibrous mineral, was once thought to be the undecahydrate, but is now believed to be chemically identical to Alum-(K).[6]

Uses

Potassium alum is an astringent/styptic and antiseptic. For this reason, it can be used as a natural deodorant by inhibiting the growth of the bacteria responsible for body odor. Use of mineral salts in such a fashion does not prevent perspiration. Its astringent/styptic properties are often employed after shaving and to reduce bleeding in minor cuts and abrasions, nosebleeds, and hemorrhoids. It is frequently used topically and internally in traditional systems of medicine including Ayurveda, where it is called phitkari or saurashtri, and traditional Chinese medicine, where it is called ming fan.[7]

References

  1. CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-130. ISBN 0-8493-0462-8.
  2. Nyburg, S. C.; Steed, J. W.; Aleksovska, S.; Petrusevski, V. M. Structure of the alums. I. On the sulfate group disorder in the α-alums. Acta Crystallogr. Sect. B: Struct. Sci. 2000, B56 (2), 204–9. DOI: 10.1107/S0108768199014846.
  3. HSNO Chemical Classification Information Database, <http://www.ermanz.govt.nz/Chemicals/ChemicalDisplay.aspx?SubstanceID=6182> (accessed 28 November 2009), New Zealand Environmental Risk Management Authority.
  4. Burke, Ernst A.J. Tidying up mineral names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks. Mineralogical Record 2008, 39 (2), 131–35, <http://pubsites.uws.edu.au/ima-cnmnc/tidyingupnames.pdf>.
  5. Alum-(K), <http://www.mindat.org/show.php?id=3267> (accessed 28 November 2009), MinDat.org. Alum-(K), <http://webmineral.com/data/Alum-%28K%29.shtml> (accessed 28 November 2009), WebMineral.com.
  6. Kalinite, <http://www.mindat.org/show.php?id=2137> (accessed 28 November 2009), MinDat.org. Kalinite, <http://webmineral.com/data/Kalinite.shtml> (accessed 28 November 2009), WebMineral.com.
  7. Uses of Alum in Traditional Chinese Medicine, <http://tcm.health-info.org/Herbology.Materia.Medica/mingfan-properties.htm>. (accessed 28 November 2009).

External links

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