Caesium hexafluorosilicate

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Caesium hexaflurosilicate
IUPAC name Caesium hexafluoridosilicate
Other names Caesium fluorosilicate
Caesium fluosilicate
Identifiers
InChI InChI=1/2Cs.F6Si/c;;1-7(2,3,4,5)6/q2*+1;-2
InChIKey GPCOEBKPRWAIIW-UHFFFAOYAV
Standard InChI InChI=1S/2Cs.F6Si/c;;1-7(2,3,4,5)6/q2*+1;-2
Standard InChIKey GPCOEBKPRWAIIW-UHFFFAOYSA-N
CAS number [16923-87-8]
ChemSpider 11254697
Properties[1]
Chemical formula Cs2SiF6
Molar mass 407.89 g/mol
Density 3.372 g/cm3, solid (17 ºC)
Solubility in water 60 g/100 ml (17 ºC)
Solubility in ethanol insoluble
Hazards[2]
EU index number 009-012-00-0
GHS pictograms Acute Tox. (oral, skin, inhal.) 3
GHS signal word DANGER
GHS hazard statements H331, H311, H301
Flash point non-flammable
Related compounds
Other anions Caesium tetrafluoroaluminate
Other cations Lithium hexafluorosilicate
Sodium hexafluorosilicate
Potassium hexafluorosilicate
Rubidium hexafluorosilicate
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Caesium hexafluorosilicate, also known simply as caesium fluorosilicate, Cs2SiF6, is the caesium salt of hexafluorosilicic acid. It is prepared by the reaction between hexafluorosilicic acid and caesium hydroxide:[3]

2CsOH + H2SiF6 → Cs2SiF6 + 2H2O

It is used as a brazing flux, especially for aluminium alloys.[3]

References

  1. CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-91. ISBN 0-8493-0462-8.
  2. Index no. 009-012-00-0 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 364.
  3. 3.0 3.1 Meshri, Dayal T.; Meshri, Sanjay D.; Contractor, Dinshaw B., et al. (Advance Research Chemicals, Inc.) Brazing flux. US Patent 5785770, published 22 November 1998.

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