Hypobromite
| Hypobromite | |
|---|---|
| Other names | Oxidobromate(1−) |
| Identifiers | |
| InChI | InChI=1/BrO/c1-2/q-1 |
| InChIKey | JGJLWPGRMCADHB-UHFFFAOYAN |
| Standard InChI | InChI=1S/BrO/c1-2/q-1 |
| Standard InChIKey | JGJLWPGRMCADHB-UHFFFAOYSA-N |
| CAS number | [] |
| ChemSpider | |
| Structure[1] | |
| Molecular geometry | r(Br–O) = 181 pm |
| Thermochemistry[2] | |
| Std enthalpy of formation ΔfH |
−91.5 kJ mol−1 (aq) |
| Std Gibbs energy of formation ΔfG |
−33.4 kJ mol−1 (aq) |
| Standard molar entropy S |
50.2 J K−1 mol−1 (aq) |
| Related compounds | |
| Other anions | Hypochlorite Bromite Bromate Perbromate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
A hypobromite is a salt or ester of hypobromous acid.
Notes and references
Notes
References
- ↑ Levason, William; Ogden, J. Steven; Spicer, Mark D.; Young, Nigel A. Characterisation of the oxo-anions of bromine BrOx− (x = 1–4) by infrared, Raman, nuclear magnetic resonance, and bromine K-edge extended X-ray absorption fine structure techniques. J. Chem. Soc., Dalton Trans. 1990 (1), 349–53. DOI: 10.1039/DT9900000349.
- ↑ Lee, C. L.; Lister, M. W. The Decomposition of Aqueous Sodium Bromite. Can. J. Chem. 1971, 49 (17), 2822–26. DOI: 10.1139/v71-470.
Further reading
- Engel, P.; Oplatka, A.; Perlmutter-Hayman, B. The Decomposition of Hypobromite and Bromite Solutions. J. Am. Chem. Soc. 1954, 76 (7), 2010–15. DOI: 10.1021/ja01636a092.
- Polak, H. L.; Feenstra, G.; Slagman, J. Stability of hypobromite solutions. Talanta 1966, 13 (5), 715–24. DOI: 10.1016/0039-9140(66)80006-1.
External links
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See also the corresponding article on Wikipedia. |
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