Difference between revisions of "Manganese tetrafluoride"
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| − | '''Manganese tetrafluoride''', MnF<sub>4</sub>, is the highest [[fluoride]] of [[manganese]]. It is used as a powerful [[oxidizing agent]] and as a means of purifying elemental [[fluorine]].<ref>{{citation | inventor1-last = Torisu | inventor1-first = Junichi | inventor2-last = Oka | inventor2-first = Masakazu | inventor3-last = Kuznetsov | inventor3-first = Andrey Sergeyevich | inventor4-last = Petrov | inventor4-first = Yury Alexeyevich | assignee = Astor Electronics/Showa Denko | title = Method of | + | '''Manganese tetrafluoride''', MnF<sub>4</sub>, is the highest [[fluoride]] of [[manganese]]. It is used as a powerful [[oxidizing agent]] and as a means of purifying elemental [[fluorine]].<ref>{{citation | inventor1-last = Torisu | inventor1-first = Junichi | inventor2-last = Oka | inventor2-first = Masakazu | inventor3-last = Kuznetsov | inventor3-first = Andrey Sergeyevich | inventor4-last = Petrov | inventor4-first = Yury Alexeyevich | assignee = Astor Electronics/Showa Denko | title = Method of manufacturing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2006033480 | publication-date = 2006-03-30}}.</ref><ref>{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Process for the purification of elemental fluorine | country-code = WO | description = PCT Appl. | publication-number = 2009074562 | publication-date = 2009-06-18}}.</ref> |
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==Preparation== | ==Preparation== | ||
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*{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}. | *{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}. | ||
*{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}. | *{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}. | ||
| − | *{{citation | inventor1-last = | + | *{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Method for preparing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2009/074560 | publication-date = 2009-06-18}}. |
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==External links== | ==External links== | ||
Revision as of 08:02, 11 September 2010
| Manganese tetrafluoride | |
|---|---|
| IUPAC name | manganese tetrafluoride |
| Other names | manganese(IV) fluoride |
| Identifiers | |
| InChI | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Properties | |
| Chemical formula | MnF4 |
| Molar mass | 130.93 g mol−1 |
| Appearance | blue solid |
| Melting point |
70 °C decomp. |
| Solubility in water | reacts violently |
| Related compounds | |
| Other cations | Manganese(II) fluoride Manganese(III) fluoride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1][2]
Contents
Preparation
Notes and references
Notes
References
- ↑ Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. (Astor Electronics/Showa Denko) Method of manufacturing manganese tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
- ↑ Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Process for the purification of elemental fluorine. WO PCT Appl. 2009074562, published 18 June 2009.
Further reading
- Roesky, H.; Glemser, O. A New Preparation of Manganese Tetrafluoride. Angew. Chem., Int. Ed. Engl. 1963, 2 (10), 626. DOI: 10.1002/anie.196306262.
- Gubkina, N. I.; Sokolov, Sergey V.; Krylov, E. I. Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds. Russ. Chem. Rev. 1966, 35 (12), 930–41. DOI: 10.1070/RC1966v035n12ABEH001550.
- Hoppe, R.; Müller, B.; Burgess, J.; Peacock, R. D.; Sherry, R. The enthalpy of formation of manganese tetrafluoride. J. Fluorine Chem. 1980, 16 (2), 189–91. DOI: 10.1016/S0022-1139(00)82393-3.
- Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Method for preparing manganese tetrafluoride. WO PCT Appl. 2009/074560, published 18 June 2009.
External links
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See also the corresponding article on Wikipedia. |
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