Difference between revisions of "Manganese tetrafluoride"

From WikiChem
Jump to: navigation, search
(Further reading)
Line 39: Line 39:
 
*{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}.
 
*{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}.
 
*{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}.
 
*{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}.
 +
*{{citation | first = Karl O. | last = Christe | year = 1986 | title = Chemical synthesis of elemental fluorine | journal = Inorg. Chem. | volume = 25 | issue = 21 | pages = 3721–24 | doi = 10.1021/ic00241a001}}.
 
*{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Method for preparing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2009/074560 | publication-date = 2009-06-18}}.
 
*{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Method for preparing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2009/074560 | publication-date = 2009-06-18}}.
  

Revision as of 23:00, 11 September 2010

Manganese tetrafluoride
IUPAC name manganese tetrafluoride
Other names manganese(IV) fluoride
Identifiers
InChI InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4
Properties
Chemical formula MnF4
Molar mass 130.93 g mol−1
Appearance blue solid
Melting point

70 °C decomp.

Solubility in water reacts violently
Related compounds
Other cations Manganese(II) fluoride
Manganese(III) fluoride
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1][2]

Preparation

Notes and references

Notes

References

  1. Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. (Astor Electronics/Showa Denko) Method of manufacturing manganese tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
  2. Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Process for the purification of elemental fluorine. WO PCT Appl. 2009074562, published 18 June 2009.

Further reading

External links

Error creating thumbnail: Unable to save thumbnail to destination
This page is currently licensed under the Creative Commons Attribution 3.0 Unported license and any later versions of that license.