Difference between revisions of "Manganese tetrafluoride"
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| OtherNames = manganese(IV) fluoride | | OtherNames = manganese(IV) fluoride | ||
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
| − | | CASNo = | + | | CASNo = 15195-58-1 |
| ChemSpiderID = | | ChemSpiderID = | ||
| InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 | | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 | ||
| − | | StdInChI= | + | | StdInChI=1S/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| InChIKey = | | InChIKey = | ||
| − | | StdInChIKey = | + | | StdInChIKey = KWKYNMDHPVYLQQ-UHFFFAOYSA-J |
| EC-number = | | EC-number = | ||
}} | }} | ||
Revision as of 04:14, 12 September 2010
| Manganese tetrafluoride | |
|---|---|
| IUPAC name | manganese tetrafluoride |
| Other names | manganese(IV) fluoride |
| Identifiers | |
| InChI | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Standard InChI | InChI=1S/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Standard InChIKey | KWKYNMDHPVYLQQ-UHFFFAOYSA-J |
| CAS number | [] |
| Properties | |
| Chemical formula | MnF4 |
| Molar mass | 130.93 g mol−1 |
| Appearance | blue solid |
| Melting point |
70 °C decomp. |
| Solubility in water | reacts violently |
| Related compounds | |
| Other cations | Manganese(II) fluoride Manganese(III) fluoride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1][2]
Contents
Preparation
Notes and references
Notes
References
- ↑ Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. (Astor Electronics/Showa Denko) Method of manufacturing manganese tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
- ↑ Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Process for the purification of elemental fluorine. WO PCT Appl. 2009074562, published 18 June 2009.
Further reading
- Roesky, H.; Glemser, O. A New Preparation of Manganese Tetrafluoride. Angew. Chem., Int. Ed. Engl. 1963, 2 (10), 626. DOI: 10.1002/anie.196306262.
- Gubkina, N. I.; Sokolov, Sergey V.; Krylov, E. I. Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds. Russ. Chem. Rev. 1966, 35 (12), 930–41. DOI: 10.1070/RC1966v035n12ABEH001550.
- Hoppe, R.; Müller, B.; Burgess, J.; Peacock, R. D.; Sherry, R. The enthalpy of formation of manganese tetrafluoride. J. Fluorine Chem. 1980, 16 (2), 189–91. DOI: 10.1016/S0022-1139(00)82393-3.
- Christe, Karl O. Chemical synthesis of elemental fluorine. Inorg. Chem. 1986, 25 (21), 3721–24. DOI: 10.1021/ic00241a001.
- Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Method for preparing manganese tetrafluoride. WO PCT Appl. 2009/074560, published 18 June 2009.
External links
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See also the corresponding article on Wikipedia. |
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