Difference between revisions of "Barium manganate"
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| − | '''Barium manganate''', BaMnO<sub>4</sub>, is a grey-green solid, insoluble in most common solvents. It is used as an [[oxidizing agent]] in [[organic synthesis]]. | + | {{chembox |
| + | | IUPACName = barium manganate(VI) | ||
| + | | Section1 = {{Chembox Identifiers | ||
| + | | CASNo = 7787-35-1 | ||
| + | | EINECS = 232-109-6 | ||
| + | | ChemSpiderID = 2341155 | ||
| + | }} | ||
| + | | Section2 = {{Chembox Properties | ||
| + | | Reference = <ref>{{RubberBible62nd|page=B-81}}.</ref> | ||
| + | | Formula = BaMnO<sub>4</sub> | ||
| + | | MolarMass = 256.26 g mol<sup>−1</sup> | ||
| + | | Appearance = grey-green powder | ||
| + | | Density = 4.85 g cm<sup>−3</sup> | ||
| + | | Solubility = insoluble | ||
| + | }} | ||
| + | | Section7 = {{Chembox Hazards | ||
| + | | Reference = <ref name="CLP">{{CLP Regulation|index=056-002-00-7|page=438}}</ref> | ||
| + | | EUIndex = 056-002-00-7 | ||
| + | | GHSPictograms = {{GHS07|Acute Tox. 4 (oral, inhal.)}} | ||
| + | | GHSSignalWord = WARNING | ||
| + | | HPhrases = {{H-phrases|302|332}} | ||
| + | | PPhrases = {{P-phrases|261|264|270|271|301+312|304+340|330|501}} | ||
| + | }} | ||
| + | }} | ||
| + | '''Barium manganate''', BaMnO<sub>4</sub>, is a grey-green solid, insoluble in most common solvents. It is used as an [[oxidizing agent]] in [[organic synthesis]].<ref>{{citation | first1 = G. | last1 = Procter | first2 = S. V. | last2 = Ley | first3 = G. H. | last3 = Castle | contribution = Barium Manganate | title = Encyclopedia of Reagents for Organic Synthesis | editor-first = L. | editor-last = Paquette | year = 2004 | publisher = Wiley | location = New York | doi = 10.1002/047084289}}.</ref><ref>{{citation | title = Barium Manganate. A Versatile Oxidant in Organic Synthesis | first1 = Habib | last1 = Firouzabadi | first2 = Zohreh | last2 = Mostafavipoor | journal = Bull. Chem. Soc. Jpn. | volume = 56 | issue = 3 | year = 1983 | pages = 914–17 | doi = 10.1246/bcsj.56.914}}.</ref><ref>{{citation | last1 = Guziec | first1 = Frank S., Jr. | last2 = Murphy | first2 = Christopher J. | last3 = Cullen | first3 = Edward R. | title = Thermal and photochemical studies of symmetrical and unsymmetrical dihydro-1,3,4-selenadiazoles | journal = J. Chem. Soc., Perkin Trans. 1 | year = 1985 | pages = 107–13 | doi = 10.1039/P19850000107}}.</ref> | ||
==References== | ==References== | ||
{{reflist}} | {{reflist}} | ||
| + | |||
| + | ==External links== | ||
| + | *{{EHC|107|name=Barium}} | ||
| + | *{{HSG|046|name=Barium}} | ||
[[Category:Barium compounds]] | [[Category:Barium compounds]] | ||
Latest revision as of 11:53, 8 January 2011
| Barium manganate | |
|---|---|
| IUPAC name | barium manganate(VI) |
| Identifiers | |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties[1] | |
| Chemical formula | BaMnO4 |
| Molar mass | 256.26 g mol−1 |
| Appearance | grey-green powder |
| Density | 4.85 g cm−3 |
| Solubility in water | insoluble |
| Hazards[2] | |
| EU index number | 056-002-00-7 |
| GHS pictograms | 
|
| GHS signal word | WARNING |
| GHS hazard statements | H302, H332 |
| GHS precautionary statements | P261, P264, P270, P271, P301+312, P304+340, P330, P501 |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Barium manganate, BaMnO4, is a grey-green solid, insoluble in most common solvents. It is used as an oxidizing agent in organic synthesis.[3][4][5]
References
- ↑ CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-81. ISBN 0-8493-0462-8.
- ↑ Index no. 056-002-00-7 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 438.
- ↑ Procter, G.; Ley, S. V.; Castle, G. H. Barium Manganate. In Encyclopedia of Reagents for Organic Synthesis; Paquette, L., Ed.; Wiley: New York, 2004. DOI: 10.1002/047084289.
- ↑ Firouzabadi, Habib; Mostafavipoor, Zohreh Barium Manganate. A Versatile Oxidant in Organic Synthesis. Bull. Chem. Soc. Jpn. 1983, 56 (3), 914–17. DOI: 10.1246/bcsj.56.914.
- ↑ Guziec, Frank S., Jr.; Murphy, Christopher J.; Cullen, Edward R. Thermal and photochemical studies of symmetrical and unsymmetrical dihydro-1,3,4-selenadiazoles. J. Chem. Soc., Perkin Trans. 1 1985, 107–13. DOI: 10.1039/P19850000107.
External links
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