Difference between revisions of "Bismuth bromide"
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===Further reading=== | ===Further reading=== | ||
| − | *{{citation | inventor1-first = | + | *{{citation | inventor1-first = Hideyuki | inventor1-last = Aizawa | inventor2-first = Akio | inventor2-last = Kuroda | inventor3-first = Masahiro | inventor3-last = Minaga | inventor4-first = Koji | inventor4-last = Onishi | inventor5-first = Seikichi | inventor5-last = Matsuhisa | assignee = Toray Ind. | title = シクロヘキセンの製造方法 (Cyclohexene production method) | country-code = JP | patent-number = 51011736 | publication-date = 1976-01-30}}. |
| − | *{{citation | inventor1-first = | + | *{{citation | inventor1-first = Ashok V. | inventor1-last = Joshi | inventor2-first = William P. | inventor2-last = Sholette | assignee = Rat-O-Vac Corp | title = High energy density solid state cell | country-code = US | patent-number = 4288505 | publication-date = 1981-09-08}}. |
*{{citation | first = J. | last = Smid | journal = Makromol. Chem. Rapid Commun. | volume = 8 | pages = 543 | year = 1987}}. | *{{citation | first = J. | last = Smid | journal = Makromol. Chem. Rapid Commun. | volume = 8 | pages = 543 | year = 1987}}. | ||
| − | *{{citation | first1 = | + | *{{citation | first1 = Bernard | last1 = Boyer | first2 = El-Mehdi | last2 = Keramane | first3 = Jean-Pierre | last3 = Roque | first4 = André A. | last4 = Pavia | title = BiBr<sub>3</sub>, an efficient catalyst for the benzylation of alcohols: 2-phenyl-2-propyl, a new benzyl-type protecting group | journal = Tetrahedron Lett. | volume = 41 | issue = 16 | pages = 2891–94 | year = 2000 | doi = 10.1016/S0040-4039(00)00304-X}}. |
| + | *{{citation | first1 = Joginder S. | last1 = Bajwa | first2 = Xinglong | last2 = Jiang | first3 = Joel | last3 = Slade | first4 = Kapa | last4 = Prasad | first5 = Oljan | last5 = Repič | first6 = Thomas J. | last6 = Blacklock | title = In-situ generation of Et<sub>3</sub>SiBr from BiBr<sub>3</sub> and Et<sub>3</sub>SiH and its use in preparation of dialkyl ethers | journal = Tetrahedron Letters | volume = 43 | issue = 38 | year = 2002 | pages = 6709–13 | doi = 10.1016/S0040-4039(02)01532-0}}. | ||
==External links== | ==External links== | ||
Revision as of 16:10, 8 January 2011
| Bismuth bromide | |
|---|---|
| Other names | Bismuth(III) bromide Bismuth tribromide |
| Identifiers | |
| InChI | InChI=1/Be.2BrH/h;2*1H/q+2;;/p-2 |
| InChIKey | PBKYCFJFZMEFRS-NUQVWONBAJ |
| Standard InChI | InChI=1S/Be.2BrH/h;2*1H/q+2;;/p-2 |
| Standard InChIKey | PBKYCFJFZMEFRS-UHFFFAOYSA-L |
| CAS number | [] |
| ChemSpider | |
| Properties[1] | |
| Chemical formula | BiBr3 |
| Molar mass | 168.82 g mol−1 |
| Appearance | off-white solid |
| Density | 5.72 g cm−3 |
| Melting point |
218 °C |
| Boiling point |
453 °C subl. |
| Solubility in water | hydrolyzes |
| Thermochemistry[2] | |
| Std enthalpy of formation ΔfH |
−355.64 kJ mol−1 |
| Standard molar entropy S |
100.37 J K−1 mol−1 |
| Hazards[3][4] | |
| EU index number | 004-002-00-2 |
| GHS pictograms |   
|
| GHS signal word | DANGER |
| GHS hazard statements | H350, H330, H301, H372, H319, H335, H315, H317, H411 |
| GHS precautionary statements | P201, P202, P260, P261, P264, P270, P271, P272, P273, P280, P281, P284, P301+312, P302+352 |
| PEL (U.S.) | 0.002 mg m−3 TWA (as Be) 0.005 mg m−3 30 min. (as Be) 0.025 mg m−3 peak (as Be) |
| Related compounds | |
| Other anions | Bismuth(III) fluoride Bismuth chloride Bismuth iodide |
| Other cations | Nitrogen tribromide Phosphorus tribromide Arsenic tribromide Antimony tribromide |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Bismuth bromide, BiBr3, is the only well-characterized bromide of bismuth. It is used as an adhesive for polyvinyl alcohol.[5][6]
Notes and references
Notes
References
- ↑ CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-82. ISBN 0-8493-0462-8.
- ↑ Beryllium bromide. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/cbook.cgi?ID=C7787464&Units=SI&Mask=7>. (accessed 8 January 2011).
- ↑ Index no. 004-002-00-2 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 341.
- ↑ "Beryllium and beryllium compounds (as Be)" in 29 C.F.R. § 1910.1000 Table Z-2, 62 FR 42018, August 4, 1997, as amended by 71 FR 36009, June 23, 2006. Beryllium and beryllium compounds. In Pocket Guide to Chemical Hazards; U.S. Department of Health and Human Services (NIOSH) Publication No. 2005-149; Government Printing Office: Washington, DC, 2005. ISBN 9780160727511, <http://www.cdc.gov/niosh/npg/npgd0054.html>.
- ↑ Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
- ↑ Kawada, J.; Fujita, M.; Harayama, T. (Nippon Synthesis Chem. Ind.) ポリビニルアルコール系成形物を接着する方法 (Method for gluing polyvinyl alcohol based moldings). JP Patent 48020013, published 18 June 1973.
Further reading
- Aizawa, Hideyuki; Kuroda, Akio; Minaga, Masahiro, et al. (Toray Ind.) シクロヘキセンの製造方法 (Cyclohexene production method). JP Patent 51011736, published 30 January 1976.
- Joshi, Ashok V.; Sholette, William P. (Rat-O-Vac Corp) High energy density solid state cell. US Patent 4288505, published 8 September 1981.
- Smid, J. Makromol. Chem. Rapid Commun. 1987, 8, 543.
- Boyer, Bernard; Keramane, El-Mehdi; Roque, Jean-Pierre; Pavia, André A. BiBr3, an efficient catalyst for the benzylation of alcohols: 2-phenyl-2-propyl, a new benzyl-type protecting group. Tetrahedron Lett. 2000, 41 (16), 2891–94. DOI: 10.1016/S0040-4039(00)00304-X.
- Bajwa, Joginder S.; Jiang, Xinglong; Slade, Joel; Prasad, Kapa; Repič, Oljan; Blacklock, Thomas J. In-situ generation of Et3SiBr from BiBr3 and Et3SiH and its use in preparation of dialkyl ethers. Tetrahedron Letters 2002, 43 (38), 6709–13. DOI: 10.1016/S0040-4039(02)01532-0.
External links
 |
See also the corresponding article on Wikipedia. |
- WebElements
- Bismuth: UK Poison Information Document
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