Difference between revisions of "Caesium cadmium chloride"
Physchim62 (talk | contribs) (start hazards) |
Physchim62 (talk | contribs) |
||
| Line 16: | Line 16: | ||
}} | }} | ||
| Section7 = {{Chembox Hazards | | Section7 = {{Chembox Hazards | ||
| + | | Reference = <ref>{{CLP Regulation|index=048-001-00-5|page=430}}</ref><ref>{{CFR cadmium}}.</ref> | ||
| EUIndex = 048-001-00-5 <!-- hazards as a cadmium compound --> | | EUIndex = 048-001-00-5 <!-- hazards as a cadmium compound --> | ||
| + | | GHSPictograms = {{GHS07|Acute Tox. (inhal., skin, oral) 4}}{{GHS09|Aquatic Acute 1, Aquatic Chronic 1}} | ||
| + | | GHSSignalWord = WARNING | ||
| + | | HPhrases = {{H-phrases|332|312|302|400|410}} | ||
| FlashPt = non-flammable | | FlashPt = non-flammable | ||
| + | | PEL = 0.005 mg/m<sup>3</sup> (as Cd) | ||
| + | }} | ||
| + | | Section8 = {{Chembox Related | ||
| + | | OtherAnions = [[Caesium cadmium bromide]] | ||
}} | }} | ||
}} | }} | ||
| Line 29: | Line 37: | ||
*{{citation | first1 = K. S. | last1 = Ahn | first2 = R. A. | last2 = Carranza | first3 = D. | last3 = Elwell | first4 = R. S. | last4 = Feigelson | title = Crystal growth of cesium cadmium chloride CsCdCl<sub>3</sub> | journal = J. Cryst. Growth | volume = 50 | issue = 4 | year = 1980 | pages = 775–78 | doi = 10.1016/0022-0248(80)90138-4}}. | *{{citation | first1 = K. S. | last1 = Ahn | first2 = R. A. | last2 = Carranza | first3 = D. | last3 = Elwell | first4 = R. S. | last4 = Feigelson | title = Crystal growth of cesium cadmium chloride CsCdCl<sub>3</sub> | journal = J. Cryst. Growth | volume = 50 | issue = 4 | year = 1980 | pages = 775–78 | doi = 10.1016/0022-0248(80)90138-4}}. | ||
*{{citation | first1 = G. C. | last1 = Cheng | first2 = D. | last2 = Elwell | title = Thermal diffusivity of cesium cadmium chloride | journal = J. Cryst. Growth | volume = 83 | issue = 1 | year = 1987 | pages = 44–46 | doi = 10.1016/0022-0248(87)90500-8}}. | *{{citation | first1 = G. C. | last1 = Cheng | first2 = D. | last2 = Elwell | title = Thermal diffusivity of cesium cadmium chloride | journal = J. Cryst. Growth | volume = 83 | issue = 1 | year = 1987 | pages = 44–46 | doi = 10.1016/0022-0248(87)90500-8}}. | ||
| + | *{{IARC cadmium}}. | ||
[[Category:Caesium compounds]] | [[Category:Caesium compounds]] | ||
| Line 35: | Line 44: | ||
[[Category:Metal halides]] | [[Category:Metal halides]] | ||
[[Category:Optical materials]] | [[Category:Optical materials]] | ||
| + | [[Category:IARC Group 1 carcinogens]] | ||
{{Imported from Wikipedia|name=Caesium cadmium chloride|id=284331233}} | {{Imported from Wikipedia|name=Caesium cadmium chloride|id=284331233}} | ||
Latest revision as of 06:31, 25 August 2009
| Caesium cadmium chloride | |
|---|---|
| IUPAC name | Caesium cadmium chloride |
| Properties | |
| Chemical formula | CsCdCl3 |
| Molar mass | 351.68 g/mol |
| Appearance | White or colourless solid |
| Structure[1] | |
| Crystal structure | Hexagonal |
| Space group | P63/mmc, No. 194 |
| Lattice constant | a = 740.3 pm, c = 1840.6 pm |
| Coordination geometry | Cd2+: D3d, C3v |
| Hazards[2][3] | |
| EU index number | 048-001-00-5 |
| GHS pictograms |  
|
| GHS signal word | WARNING |
| GHS hazard statements | H332, H312, H302, H400, H410 |
| Flash point | non-flammable |
| PEL (U.S.) | 0.005 mg/m3 (as Cd) |
| Related compounds | |
| Other anions | Caesium cadmium bromide |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Caesium cadmium chloride (CsCdCl3) is a synthetic crystalline material. It belongs to the AMX3 group, where A = an alkali metal, M = a bivalent metal and X = a halide. It is formed from an aqueous solution of hydrochloric acid containing equimolar quantities of caesium chloride and cadmium chloride.[4]
References
- ↑ Chang, Jin Rong; McPherson, Gary L.; Atwood, Jerry L. Electron paramagnetic resonance spectra of vanadium(II) and nickel(II) doped into crystals of cesium cadmium chloride and a redetermination of the structure of cesium cadmium chloride. Inorg. Chem. 1975, 14 (12), 3079–85. DOI: 10.1021/ic50154a044.
- ↑ Index no. 048-001-00-5 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 430.
- ↑ 29 CFR 1910.1027 (57 FR 42389, Sept. 14, 1992, as amended).
- ↑ McPherson, Gary L.; Chang, Jin Rong Electron paramagnetic spectrum of manganese(II)–manganese(II) pairs in single crystals of cesium cadmium chloride. Electronic structure of the nonachlorodimanganate(5–) dimer. Inorg. Chem. 1976, 15 (5), 1018–22. DOI: 10.1021/ic50159a006.
Further reading
- Ahn, K. S.; Carranza, R. A.; Elwell, D.; Feigelson, R. S. Crystal growth of cesium cadmium chloride CsCdCl3. J. Cryst. Growth 1980, 50 (4), 775–78. DOI: 10.1016/0022-0248(80)90138-4.
- Cheng, G. C.; Elwell, D. Thermal diffusivity of cesium cadmium chloride. J. Cryst. Growth 1987, 83 (1), 44–46. DOI: 10.1016/0022-0248(87)90500-8.
- Cadmium and Cadmium Compounds. In Beryllium, Cadmium, Mercury, and Exposures in the Glass Manufacturing Industry; IARC Monographs on the Evaluation of Carcinogenic Risks to Humans 58; International Agency for Research on Cancer: Lyon, France, 1993; pp 119–237. ISBN 92-832-1258-4, <http://monographs.iarc.fr/ENG/Monographs/vol58/mono58-7.pdf>.
| Error creating thumbnail: Unable to save thumbnail to destination |  |
This page was originally imported from Wikipedia, specifically this version of the article "Caesium cadmium chloride". Please see the history page on Wikipedia for the original authors. This WikiChem article may have been modified since it was imported. It is licensed under the Creative Commons Attribution–Share Alike 3.0 Unported license. |
