Difference between revisions of "Caesium nitrate"
Physchim62 (talk | contribs) (Imported from http://en.wikipedia.org/w/index.php?title=Caesium_nitrate&oldid=309988773) |
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{{chembox | {{chembox | ||
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| Name = Caesium nitrate | | Name = Caesium nitrate | ||
| Section1 = {{Chembox Identifiers | | Section1 = {{Chembox Identifiers | ||
| InChI = 1/Cs.NO3/c;2-1(3)4/q+1;-1 | | InChI = 1/Cs.NO3/c;2-1(3)4/q+1;-1 | ||
+ | | StdInChI = 1/Cs.NO3/c;2-1(3)4/q+1;-1 | ||
+ | | InChIKey = NLSCHDZTHVNDCP-UHFFFAOYAE | ||
+ | | StdInChIKey = NLSCHDZTHVNDCP-UHFFFAOYSA-N | ||
| CASNo = 7789-18-6 | | CASNo = 7789-18-6 | ||
| CASNo_Ref = {{cascite}} | | CASNo_Ref = {{cascite}} | ||
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}} | }} | ||
| Section2 = {{Chembox Properties | | Section2 = {{Chembox Properties | ||
+ | | Reference = <ref name="CRC">{{RubberBible62nd|page=B-92}}.</ref> | ||
| Formula = CsNO<sub>3</sub> | | Formula = CsNO<sub>3</sub> | ||
| MolarMass = 194.91 g/mol | | MolarMass = 194.91 g/mol | ||
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}} | }} | ||
| Section7 = {{Chembox Hazards | | Section7 = {{Chembox Hazards | ||
+ | | Reference = <ref>{{GHS class NZ|id=13721|accessdate=2009-08-25}}.</ref> | ||
| EUIndex = not listed | | EUIndex = not listed | ||
| GHSPictograms = {{GHS flame over circle|Ox. Sol. 3}} | | GHSPictograms = {{GHS flame over circle|Ox. Sol. 3}} | ||
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}} | }} | ||
}} | }} | ||
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+ | | Name = Caesium nitrate—nitric acid (1/1) | ||
+ | | Section1 = {{Chembox Identifiers | ||
+ | | InChI=1/Cs.HNO3.NO3/c;2*2-1(3)4/h;(H,2,3,4);/q+1;;-1 | ||
+ | }} | ||
+ | | Section2 = {{Chembox Properties | ||
+ | | Reference = <ref name="CRC"/> | ||
+ | | Formula = CsNO<sub>3</sub>·HNO<sub>3</sub> | ||
+ | | MolarMass = 257.92 g/mol | ||
+ | | MeltingPt = 100 ºC | ||
+ | }} | ||
+ | }} | ||
+ | {{FixBunching|mid}} | ||
+ | {{chembox | ||
+ | | Name = Caesium nitrate—nitric acid (1/2) | ||
+ | | Section1 = {{Chembox Identifiers | ||
+ | | InChI=1/Cs.2HNO3.NO3/c;3*2-1(3)4/h;2*(H,2,3,4);/q+1;;;-1 | ||
+ | }} | ||
+ | | Section2 = {{Chembox Properties | ||
+ | | Reference = <ref name="CRC"/> | ||
+ | | Formula = CsNO<sub>3</sub>·2HNO<sub>3</sub> | ||
+ | | MolarMass = 320.92 g/mol | ||
+ | | MeltingPt = 32–36 ºC | ||
+ | }} | ||
+ | }} | ||
+ | {{FixBunching|end}} | ||
'''Caesium nitrate''' is a [[chemical compound]] with the [[chemical formula]] [[caesium|Cs]][[Nitrogen|N]][[Oxygen|O]]<sub>3</sub>. It is used in [[pyrotechnic composition]]s, as a [[pyrotechnic colorant|colorant]] and an [[oxidizer]], e.g. in [[decoy flare|decoys]] and [[flare (pyrotechnic)|illumination flare]]s. The caesium emissions are chiefly due to two powerful [[spectral line]]s at 852.113 nm and 894.347 nm. | '''Caesium nitrate''' is a [[chemical compound]] with the [[chemical formula]] [[caesium|Cs]][[Nitrogen|N]][[Oxygen|O]]<sub>3</sub>. It is used in [[pyrotechnic composition]]s, as a [[pyrotechnic colorant|colorant]] and an [[oxidizer]], e.g. in [[decoy flare|decoys]] and [[flare (pyrotechnic)|illumination flare]]s. The caesium emissions are chiefly due to two powerful [[spectral line]]s at 852.113 nm and 894.347 nm. | ||
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==External links== | ==External links== | ||
− | *[http://www.frankmckinnon.com/cesium_compounds.htm Cesium Compounds: | + | *[http://www.frankmckinnon.com/cesium_compounds.htm Cesium Compounds: Nuclear Power Plant Emissions] |
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[[Category:Caesium compounds]] | [[Category:Caesium compounds]] | ||
[[Category:Nitrates]] | [[Category:Nitrates]] | ||
− | [[Category:Pyrotechnic | + | [[Category:Pyrotechnic chemicals]] |
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{{Imported from Wikipedia|name=Caesium nitrate|id=309988773}} | {{Imported from Wikipedia|name=Caesium nitrate|id=309988773}} |
Revision as of 11:00, 25 August 2009
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Caesium nitrate is a chemical compound with the chemical formula CsNO3. It is used in pyrotechnic compositions, as a colorant and an oxidizer, e.g. in decoys and illumination flares. The caesium emissions are chiefly due to two powerful spectral lines at 852.113 nm and 894.347 nm.
Caesium nitrate prisms are used in infrared spectroscopy, in x-ray phosphors, and in scintillation counters.[3] It is also used in making optical glasses and lenses.
As with other alkali metal nitrates, caesium nitrate decomposes on heating to give caesium nitrite:
- CsNO3 → CsNO2 + ½O2
Caesium also forms two unusual acid nitrates, which can be described as CsNO3·HNO3 and CsNO3·2HNO3 (melting points 100 ºC and 36–38 ºC respectively).[1]
References
- ↑ 1.0 1.1 1.2 1.3 CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-92. ISBN 0-8493-0462-8.
- ↑ HSNO Chemical Classification Information Database, <http://www.ermanz.govt.nz/Chemicals/ChemicalDisplay.aspx?SubstanceID=13721> (accessed 25 August 2009), New Zealand Environmental Risk Management Authority.
- ↑ The Merck Index: An Encyclopedia of Chemicals, Drugs, and Biologicals, 13th ed.; Budavari, Susan, Ed.; Merck, 2001; p 345. ISBN 0911910131.
External links
Error creating thumbnail: Unable to save thumbnail to destination | This page was originally imported from Wikipedia, specifically this version of the article "Caesium nitrate". Please see the history page on Wikipedia for the original authors. This WikiChem article may have been modified since it was imported. It is licensed under the Creative Commons Attribution–Share Alike 3.0 Unported license. |