Difference between revisions of "Bromate"
Physchim62 (talk | contribs) (Created page with "{{chembox | OtherNames = Trioxidobromate(1−) | Section1 = {{Chembox Identifiers | ChemSpiderID = 76658 | InChI=1/BrHO3/c2-1(3)4/h(H,2,3,4)/p-1 | InChIKey = SXDBWCPKPHAZSM...") |
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| Section3 = {{Chembox Structure | | Section3 = {{Chembox Structure | ||
| Reference = <ref>{{citation | first1 = William | last1 = Levason | first2 = J. Steven | last2 = Ogden | first3 = Mark D. | last3 = Spicer | first4 = Nigel A. | last4 = Young | title = Characterisation of the oxo-anions of bromine BrO<sub>''x''</sub><sup>−</sup> (''x'' = 1–4) by infrared, Raman, nuclear magnetic resonance, and bromine ''K''-edge extended X-ray absorption fine structure techniques | journal = J. Chem. Soc., Dalton Trans. | year = 1990 | issue = 1 | pages = 349–53 | doi = 10.1039/DT9900000349}}.</ref> | | Reference = <ref>{{citation | first1 = William | last1 = Levason | first2 = J. Steven | last2 = Ogden | first3 = Mark D. | last3 = Spicer | first4 = Nigel A. | last4 = Young | title = Characterisation of the oxo-anions of bromine BrO<sub>''x''</sub><sup>−</sup> (''x'' = 1–4) by infrared, Raman, nuclear magnetic resonance, and bromine ''K''-edge extended X-ray absorption fine structure techniques | journal = J. Chem. Soc., Dalton Trans. | year = 1990 | issue = 1 | pages = 349–53 | doi = 10.1039/DT9900000349}}.</ref> | ||
| − | | MolShape = pyramidal: ''r''(Br–O) = | + | | MolShape = pyramidal: ''r''(Br–O) = 165 pm |
}} | }} | ||
| Section4 = {{Chembox Thermochemistry | | Section4 = {{Chembox Thermochemistry | ||
Latest revision as of 07:40, 5 January 2011
| Bromate | |
|---|---|
| Other names | Trioxidobromate(1−) |
| Identifiers | |
| InChI | InChI=1/BrHO3/c2-1(3)4/h(H,2,3,4)/p-1 |
| InChIKey | SXDBWCPKPHAZSM-REWHXWOFAY |
| Standard InChI | InChI=1S/BrHO3/c2-1(3)4/h(H,2,3,4)/p-1 |
| Standard InChIKey | SXDBWCPKPHAZSM-UHFFFAOYSA-M |
| CAS number | [] |
| ChemSpider | |
| Structure[1] | |
| Molecular geometry | pyramidal: r(Br–O) = 165 pm |
| Thermochemistry[2] | |
| Std enthalpy of formation ΔfH |
−67.9 kJ mol−1 (aq) |
| Std Gibbs energy of formation ΔfG |
+18.0 kJ mol−1 (aq) |
| Standard molar entropy S |
161 J K−1 mol−1 (aq) |
| Related compounds | |
| Other anions | Chlorate Iodate Hypobromite Bromite Perbromate |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
A bromate is a salt or ester of bromic acid.
Notes and references
Notes
References
- ↑ Levason, William; Ogden, J. Steven; Spicer, Mark D.; Young, Nigel A. Characterisation of the oxo-anions of bromine BrOx− (x = 1–4) by infrared, Raman, nuclear magnetic resonance, and bromine K-edge extended X-ray absorption fine structure techniques. J. Chem. Soc., Dalton Trans. 1990 (1), 349–53. DOI: 10.1039/DT9900000349.
- ↑ Lee, C. L.; Lister, M. W. The Decomposition of Aqueous Sodium Bromite. Can. J. Chem. 1971, 49 (17), 2822–26. DOI: 10.1139/v71-470.
External links
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See also the corresponding article on Wikipedia. |
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