Difference between revisions of "Manganese tetrafluoride"
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| − | '''Manganese tetrafluoride''', MnF<sub>4</sub>, is the highest [[fluoride]] of [[manganese]]. It is used as a powerful [[oxidizing agent]] and as a means of purifying elemental [[fluorine]].<ref>{{citation | inventor1-last = Torisu | inventor1-first = Junichi | inventor2-last = Oka | inventor2-first = Masakazu | inventor3-last = Kuznetsov | inventor3-first = Andrey Sergeyevich | inventor4-last = Petrov | inventor4-first = Yury Alexeyevich | title = Method of Manufacturing Manganese Tetrafluoride | country-code = WO | | + | '''Manganese tetrafluoride''', MnF<sub>4</sub>, is the highest [[fluoride]] of [[manganese]]. It is used as a powerful [[oxidizing agent]] and as a means of purifying elemental [[fluorine]].<ref>{{citation | inventor1-last = Torisu | inventor1-first = Junichi | inventor2-last = Oka | inventor2-first = Masakazu | inventor3-last = Kuznetsov | inventor3-first = Andrey Sergeyevich | inventor4-last = Petrov | inventor4-first = Yury Alexeyevich | title = Method of Manufacturing Manganese Tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2006033480 | publication-date = 2006-03-30}}.</ref> |
==Preparation== | ==Preparation== | ||
Revision as of 07:05, 11 September 2010
| Manganese tetrafluoride | |
|---|---|
| IUPAC name | manganese tetrafluoride |
| Other names | manganese(IV) fluoride |
| Identifiers | |
| InChI | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Properties | |
| Chemical formula | MnF4 |
| Molar mass | 130.93 g mol−1 |
| Appearance | blue solid |
| Melting point |
70 °C decomp. |
| Solubility in water | reacts violently |
| Related compounds | |
| Other cations | Manganese(II) fluoride Manganese(III) fluoride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1]
Contents
Preparation
Notes and references
Notes
References
- ↑ Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. Method of Manufacturing Manganese Tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
Further reading
- Roesky, H.; Glemser, O. A New Preparation of Manganese Tetrafluoride. Angew. Chem., Int. Ed. Engl. 1963, 2 (10), 626. DOI: 10.1002/anie.196306262.
- Gubkina, N. I.; Sokolov, Sergey V.; Krylov, E. I. Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds. Russ. Chem. Rev. 1966, 35 (12), 930–41. DOI: 10.1070/RC1966v035n12ABEH001550.
- Hoppe, R.; Müller, B.; Burgess, J.; Peacock, R. D.; Sherry, R. The enthalpy of formation of manganese tetrafluoride. J. Fluorine Chem. 1980, 16 (2), 189–91. DOI: 10.1016/S0022-1139(00)82393-3.
External links
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See also the corresponding article on Wikipedia. |
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