Difference between revisions of "Manganese tetrafluoride"
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*{{citation | first1 = H. | last1 = Roesky | first2 = O. | last2 = Glemser | title = A New Preparation of Manganese Tetrafluoride | journal = Angew. Chem., Int. Ed. Engl. | volume = 2 | issue = 10 | page = 626 | year = 1963 | doi = 10.1002/anie.196306262}}. | *{{citation | first1 = H. | last1 = Roesky | first2 = O. | last2 = Glemser | title = A New Preparation of Manganese Tetrafluoride | journal = Angew. Chem., Int. Ed. Engl. | volume = 2 | issue = 10 | page = 626 | year = 1963 | doi = 10.1002/anie.196306262}}. | ||
*{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}. | *{{citation | first1 = N. I. | last1 = Gubkina | first2 = Sergey V. | last2 = Sokolov | first3 = E. I. | last3 = Krylov | title = Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds | journal = Russ. Chem. Rev. | year = 1966 | volume = 35 | issue = 12 | pages = 930–41 | doi = 10.1070/RC1966v035n12ABEH001550}}. | ||
| + | *{{citation | first1 = T. C. | last1 = Ehlert | first2 = M. | last2 = Hsia | title = Mass spectrometric and thermochemical studies of the manganese fluorides | journal = J. Fluorine Chem. | volume = 2 | issue = 1 | year = 1972 | pages = 33–51 | doi = 10.1016/S0022-1139(00)83113-9}}. | ||
*{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}. | *{{citation | first1 = R. | last1 = Hoppe | first2 = B. | last2 = Müller | first3 = J. | last3 = Burgess | first4 = R. D. | last4 = Peacock | first5 = R. | last5 = Sherry | title = The enthalpy of formation of manganese tetrafluoride | journal = J. Fluorine Chem. | volume = 16 | issue = 2 | year = 1980 | pages = 189–91 | doi = 10.1016/S0022-1139(00)82393-3}}. | ||
*{{citation | first = Karl O. | last = Christe | year = 1986 | title = Chemical synthesis of elemental fluorine | journal = Inorg. Chem. | volume = 25 | issue = 21 | pages = 3721–24 | doi = 10.1021/ic00241a001}}. | *{{citation | first = Karl O. | last = Christe | year = 1986 | title = Chemical synthesis of elemental fluorine | journal = Inorg. Chem. | volume = 25 | issue = 21 | pages = 3721–24 | doi = 10.1021/ic00241a001}}. | ||
| + | *{{citation | first1 = M. | last1 = Adelhelm | first2 = E. | last2 = Jacob | title = MnF<sub>4</sub>: preparation and properties | journal = J. Fluorine Chem. | volume = 54 | issue = 1–3 | year = 1991 | page = 21 | doi = 10.1016/S0022-1139(00)83531-9}}. | ||
| + | *{{citation | first = Z. | last = Mazej | title = Room temperature syntheses of MnF<sub>3</sub>, MnF<sub>4</sub> and hexafluoromanganete(IV) salts of alkali cations | journal = J. Fluorine Chem. | volume = 114 | issue = 1 | year = 2002 | pages = 75–80 | doi = 10.1016/S0022-1139(01)00566-8}}. | ||
*{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Method for preparing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2009/074560 | publication-date = 2009-06-18}}. | *{{citation | inventor1-last = Seseke-Koyro | inventor1-first = Ulrich | inventor2-last = Garcia-Juan | inventor2-first = Placido | inventor3-last = Palsherm | inventor3-first = Stefan | inventor4-last = Schulz | inventor4-first = Alf | assignee = Solvay Fluor | title = Method for preparing manganese tetrafluoride | country-code = WO | description = PCT Appl. | publication-number = 2009/074560 | publication-date = 2009-06-18}}. | ||
Revision as of 08:20, 12 September 2010
| Manganese tetrafluoride | |
|---|---|
| IUPAC name | manganese tetrafluoride |
| Other names | manganese(IV) fluoride |
| Identifiers | |
| InChI | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Standard InChI | InChI=1S/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
| Standard InChIKey | KWKYNMDHPVYLQQ-UHFFFAOYSA-J |
| CAS number | [] |
| Properties | |
| Chemical formula | MnF4 |
| Molar mass | 130.93 g mol−1 |
| Appearance | blue solid |
| Melting point |
70 °C decomp. |
| Solubility in water | reacts violently |
| Related compounds | |
| Other cations | Manganese(II) fluoride Manganese(III) fluoride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1][2]
Contents
Preparation
Manganese tetrafluoride was first unequivocally prepared[Note 1] in 1961 by the reaction of manganese(II) fluoride (or other MnII compounds) with a stream of fluorine gas at 550 °C: the MnF4 sublimes into the gas stream and condenses onto a cold finger.[5]
Notes and references
Notes
References
- ↑ Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. (Astor Electronics/Showa Denko) Method of manufacturing manganese tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
- ↑ Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Process for the purification of elemental fluorine. WO PCT Appl. 2009074562, published 18 June 2009.
- ↑ Melville, W. H. Contribution towards the History of the Fluorides of Manganese. Proc. Am. Acad. Arts Sci. 1876, 12, 228–34, <http://www.jstor.org/stable/25138452>.
- ↑ Weinland, R. F.; Lauenstein, O. Z. Anorg. Allg. Chem. 1899, 20, 40.
- ↑ Hoppe, Rudolf; Dähne, Wolfgang; Klemm, Wilhelm Mangantetrafluorid, MnF4. Naturwissenschaften 1961, 48 (11), 429. DOI: 10.1007/BF00621676.
Further reading
- Roesky, H.; Glemser, O. A New Preparation of Manganese Tetrafluoride. Angew. Chem., Int. Ed. Engl. 1963, 2 (10), 626. DOI: 10.1002/anie.196306262.
- Gubkina, N. I.; Sokolov, Sergey V.; Krylov, E. I. Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds. Russ. Chem. Rev. 1966, 35 (12), 930–41. DOI: 10.1070/RC1966v035n12ABEH001550.
- Ehlert, T. C.; Hsia, M. Mass spectrometric and thermochemical studies of the manganese fluorides. J. Fluorine Chem. 1972, 2 (1), 33–51. DOI: 10.1016/S0022-1139(00)83113-9.
- Hoppe, R.; Müller, B.; Burgess, J.; Peacock, R. D.; Sherry, R. The enthalpy of formation of manganese tetrafluoride. J. Fluorine Chem. 1980, 16 (2), 189–91. DOI: 10.1016/S0022-1139(00)82393-3.
- Christe, Karl O. Chemical synthesis of elemental fluorine. Inorg. Chem. 1986, 25 (21), 3721–24. DOI: 10.1021/ic00241a001.
- Adelhelm, M.; Jacob, E. MnF4: preparation and properties. J. Fluorine Chem. 1991, 54 (1–3), 21. DOI: 10.1016/S0022-1139(00)83531-9.
- Mazej, Z. Room temperature syntheses of MnF3, MnF4 and hexafluoromanganete(IV) salts of alkali cations. J. Fluorine Chem. 2002, 114 (1), 75–80. DOI: 10.1016/S0022-1139(01)00566-8.
- Seseke-Koyro, Ulrich; Garcia-Juan, Placido; Palsherm, Stefan, et al. (Solvay Fluor) Method for preparing manganese tetrafluoride. WO PCT Appl. 2009/074560, published 18 June 2009.
External links
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See also the corresponding article on Wikipedia. |
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