Difference between revisions of "Sulfur dichloride"
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| BoilingPt = 60 °C | | BoilingPt = 60 °C | ||
| Solubility = reacts violently | | Solubility = reacts violently | ||
| + | }} | ||
| + | | Section3 = {{Chembox Structure | ||
| + | | Reference = <ref>{{Greenwood&Earnshaw1st|pages=815–16}}.</ref> | ||
| + | | MolShape = bent | ||
| + | | SpaceGroup = | ||
| + | | Coordination = | ||
| + | | LattConst_a = | ||
| + | | LattConst_c = | ||
}} | }} | ||
| Section4 = {{Chembox Thermochemistry | | Section4 = {{Chembox Thermochemistry | ||
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| DeltaHf = −49.79 kJ mol<sup>−1</sup> | | DeltaHf = −49.79 kJ mol<sup>−1</sup> | ||
| Entropy = 183.68 J K<sup>−1</sup> mol<sup>−1</sup> | | Entropy = 183.68 J K<sup>−1</sup> mol<sup>−1</sup> | ||
| + | }} | ||
| + | | Section7 = {{Chembox Hazards | ||
| + | | Reference = <ref>{{CLP Regulation|index=013-003-00-7|page=366}}</ref> | ||
| + | | ExternalMSDS = {{ICSC-small|1661}} | ||
| + | | EUIndex = 016-013-00-X | ||
| + | | GHSPictograms = {{GHS05|Skin Corr. 1B}}{{GHS07|STOT SE 3}}{{GHS09|Aquatic Acute 1}} | ||
| + | | GHSSignalWord = DANGER | ||
| + | | HPhrases = {{H-phrases|314|335|400}} | ||
}} | }} | ||
| Section8 = {{Chembox Related | | Section8 = {{Chembox Related | ||
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[[Category:Sulfur compounds]] | [[Category:Sulfur compounds]] | ||
[[Category:Chlorides]] | [[Category:Chlorides]] | ||
| − | [[Category: | + | [[Category:Nonmetal halides]] |
{{CC-BY-3.0}} | {{CC-BY-3.0}} | ||
Revision as of 13:47, 17 September 2010
| Sulfur dichloride | |
|---|---|
| IUPAC name | sulfur dichloride |
| Other names | dichlorosulfane |
| Identifiers | |
| InChI | InChI=1/Cl2S/c1-3-2 |
| InChIKey | FWMUJAIKEJWSSY-UHFFFAOYAS |
| Standard InChI | InChI=1S/Cl2S/c1-3-2 |
| Standard InChIKey | FWMUJAIKEJWSSY-UHFFFAOYSA-N |
| CAS number | [] |
| EC number | |
| ChemSpider | |
| Properties | |
| Chemical formula | SCl2 |
| Molar mass | 102.97 g mol−1 |
| Appearance | red liquid |
| Density | 1.621 g cm−3 |
| Melting point |
−122 °C |
| Boiling point |
60 °C |
| Solubility in water | reacts violently |
| Structure[1] | |
| Molecular geometry | bent |
| Thermochemistry[2] | |
| Std enthalpy of formation ΔfH |
−49.79 kJ mol−1 |
| Standard molar entropy S |
183.68 J K−1 mol−1 |
| Hazards[3] | |
| Material safety data sheet (MSDS) | ICSC |
| EU index number | 016-013-00-X |
| GHS pictograms |   
|
| GHS signal word | DANGER |
| GHS hazard statements | H314, H335, H400 |
| Related compounds | |
| Other chlorides of sulfur | Disulfur dichloride Sulfur tetrachloride |
| Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) | |
Sulfur dichloride, SCl2, is the highest thermally stable chloride of sulfur.
Notes and references
Notes
References
- ↑ Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 815–16. ISBN 0-08-022057-6.
- ↑ Sulfur dichloride. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3DInChI=1S/Cl2S/c1-3-2>. (accessed 17 September 2010).
- ↑ Index no. 013-003-00-7 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 366.
External links
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See also the corresponding article on Wikipedia. |
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