Manganese tetrafluoride
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Manganese tetrafluoride | |
---|---|
IUPAC name | manganese tetrafluoride |
Other names | manganese(IV) fluoride |
Identifiers | |
InChI | InChI=1/4FH.Mn/h4*1H;/q;;;;+4/p-4 |
Properties | |
Chemical formula | MnF4 |
Molar mass | 130.93 g mol−1 |
Appearance | blue solid |
Melting point |
70 °C decomp. |
Solubility in water | reacts violently |
Related compounds | |
Other cations | Manganese(II) fluoride Manganese(III) fluoride |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Manganese tetrafluoride, MnF4, is the highest fluoride of manganese. It is used as a powerful oxidizing agent and as a means of purifying elemental fluorine.[1]
Contents
Preparation
Notes and references
Notes
References
- ↑ Torisu, Junichi; Oka, Masakazu; Kuznetsov, Andrey Sergeyevich, et al. Method of Manufacturing Manganese Tetrafluoride. WO PCT Appl. 2006033480, published 30 March 2006.
Further reading
- Roesky, H.; Glemser, O. A New Preparation of Manganese Tetrafluoride. Angew. Chem., Int. Ed. Engl. 1963, 2 (10), 626. DOI: 10.1002/anie.196306262.
- Gubkina, N. I.; Sokolov, Sergey V.; Krylov, E. I. Fluorides of High Oxidising Power and Their Application to the Preparation of Organic Fluorine Compounds. Russ. Chem. Rev. 1966, 35 (12), 930–41. DOI: 10.1070/RC1966v035n12ABEH001550.
- Hoppe, R.; Müller, B.; Burgess, J.; Peacock, R. D.; Sherry, R. The enthalpy of formation of manganese tetrafluoride. J. Fluorine Chem. 1980, 16 (2), 189–91. DOI: 10.1016/S0022-1139(00)82393-3.
External links
See also the corresponding article on Wikipedia. |
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