Sulfur dichloride

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Sulfur dichloride
IUPAC name sulfur dichloride
Other names dichlorosulfane
Identifiers
InChI InChI=1/Cl2S/c1-3-2
InChIKey FWMUJAIKEJWSSY-UHFFFAOYAS
Standard InChI InChI=1S/Cl2S/c1-3-2
Standard InChIKey FWMUJAIKEJWSSY-UHFFFAOYSA-N
CAS number [10545-99-0]
EC number 234-129-0
ChemSpider 23682
Properties
Chemical formula SCl2
Molar mass 102.97 g mol−1
Appearance red liquid
Density 1.621 g cm−3
Melting point

−122 °C

Boiling point

60 °C

Solubility in water reacts violently
Structure[1]
Molecular geometry bent
Thermochemistry[2]
Std enthalpy of formation ΔfHo298 −49.79 kJ mol−1
Standard molar entropy So298 183.68 J K−1 mol−1
Hazards[3]
Material safety data sheet (MSDS) ICSC 1661
EU index number 016-013-00-X
GHS pictograms Skin Corr. 1BSTOT SE 3Aquatic Acute 1
GHS signal word DANGER
GHS hazard statements H314, H335, H400
Related compounds
Other chlorides of sulfur Disulfur dichloride
Sulfur tetrachloride
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Sulfur dichloride, SCl2, is the highest thermally stable chloride of sulfur.

Notes and references

Notes

References

  1. Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 815–16. ISBN 0-08-022057-6.
  2. Sulfur dichloride. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3DInChI=1S/Cl2S/c1-3-2>. (accessed 17 September 2010).
  3. Index no. 013-003-00-7 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 366.

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