Disulfur dichloride
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Disulfur dichloride | |
---|---|
IUPAC name | sulfur dichloride |
Other names | dichlorosulfane |
Identifiers | |
InChI | InChI=1/Cl2S2/c1-3-4-2 |
InChIKey | PXJJSXABGXMUSU-UHFFFAOYAK |
Standard InChI | InChI=1S/Cl2S2/c1-3-4-2 |
Standard InChIKey | PXJJSXABGXMUSU-UHFFFAOYSA-N |
CAS number | [ | ]
EC number | |
ChemSpider | |
Properties[1] | |
Chemical formula | S2Cl2 |
Molar mass | 135.04 g mol−1 |
Appearance | yellow liquid |
Density | 1.677 g cm−3 |
Melting point |
−76 °C |
Boiling point |
138 °C |
Solubility in water | reacts violently |
Structure[1] | |
Molecular geometry | bent; S–S = 195 pm, S–Cl = 206 pm, Cl–S–S = 107.7°, dihedral = 85.2° |
Thermochemistry[2] | |
Std enthalpy of formation ΔfH |
−58.16 kJ mol−1 |
Standard molar entropy S |
223.84 J K−1 mol−1 |
Hazards[3] | |
Material safety data sheet (MSDS) | ICSC |
EU index number | 016-012-00-4 |
GHS pictograms | |
GHS signal word | DANGER |
GHS hazard statements | H301, H332, H314, H400 |
Related compounds | |
Other anions | Disulfur difluoride Disulfur dibromide Disulfur diiodide |
Other cations | Diselenium dichloride |
Other chlorides of sulfur | Sulfur dichloride Sulfur tetrachloride Thionyl chloride Sulfuryl chloride |
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) |
Disulfur dichloride, S2Cl2, is the most common chloride of sulfur.
Notes and references
Notes
References
- ↑ 1.0 1.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 815–16, 820. ISBN 0-08-022057-6.
- ↑ Disulfur dichloride. In NIST Chemistry WebBook; National Institute for Standards and Technology, <http://webbook.nist.gov/cgi/inchi/InChI%3DInChI=1S/Cl2S2/c1-3-4-2>. (accessed 17 September 2010).
- ↑ Index no. 016-012-00-4 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 399.
External links
See also the corresponding article on Wikipedia. |
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