Potassium hypobromite

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Potassium hypobromate trihydrate
IUPAC name Potassium hypobromite — water (1/3)
Other names Potassium bromate(I)
Identifiers
InChI InChI=1/BrO.K.5H2O/c1-2;;;;;;/h;;5*1H2/q-1;+1;;;;;
Standard InChI InChI=1S/BrO.K.5H2O/c1-2;;;;;;/h;;5*1H2/q-1;+1;;;;;
Standard InChIKey HEVCOVLJVKIYEP-UHFFFAOYSA-N
CAS number [13824-97-0]
Properties
Chemical formula KBrO·3H2O
Molar mass 189.05 g mol−1
Related compounds
Other anions Potassium hypochlorite
Other cations Lithium hypobromite
Sodium hypobromite
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Potassium hypobromite
Identifiers
InChI InChI=1/BrO.K/c1-2;/q-1;+1
InChIKey ORQYPOUSZINNCB-UHFFFAOYAZ
Standard InChI InChI=1S/BrO.K/c1-2;/q-1;+1
Standard InChIKey ORQYPOUSZINNCB-UHFFFAOYSA-N
ChemSpider 8074495
Properties
Chemical formula KBrO
Molar mass 135.00 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Potassium hypobromite, KBrO, is the potassium salt of hypobromous acid. It can be prepared by the reaction of bromine with aqueous potassium hydroxide solution at 0 °C or lower.[1][2] It has long been known as a strong oxidizing agent in solution,[3] but the solid trihydrate was not isolated until 1952.[2]

Notes and references

Notes

References

  1. Cotton, F. Albert; Wilkinson, Geoffrey Advanced Inorganic Chemistry, 5th ed.; Wiley-Interscience: New York, 1988; pp 563–67. ISBN 0-471-84997-9.
  2. 2.0 2.1 Scholder, R.; Krauss, K. Über Kristallisierte Alkalihypobromite. Z. Anorg. Allg. Chem. 1952, 268 (4–6), 279–90. DOI: 10.1002/zaac.19522680410.
  3. Tomíček, O.; Jašek, M. Volumetric Determinations in Strongly Alkaline Solutions. III. The Titration of Thallium and Cerium with Hypobromite. J. Am. Chem. Soc. 1935, 57 (12), 2409–11. DOI: 10.1021/ja01315a026.
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