Potassium hypobromite

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Potassium hypobromate trihydrate
IUPAC name Potassium hypobromite — water (1/3)
Other names Potassium bromate(I)
Identifiers
InChI InChI=1/BrO.K.5H2O/c1-2;;;;;;/h;;5*1H2/q-1;+1;;;;;
Standard InChI InChI=1S/BrO.K.5H2O/c1-2;;;;;;/h;;5*1H2/q-1;+1;;;;;
Standard InChIKey HEVCOVLJVKIYEP-UHFFFAOYSA-N
CAS number [13824-97-0]
Properties
Chemical formula KBrO·3H2O
Molar mass 189.05 g mol−1
Related compounds
Other anions Potassium hypochlorite
Other cations Lithium hypobromite
Sodium hypobromite
Other compounds Potassium bromide
Potassium bromite
Potassium bromate
Potassium perbromate
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)
Potassium hypobromite
Identifiers
InChI InChI=1/BrO.K/c1-2;/q-1;+1
InChIKey ORQYPOUSZINNCB-UHFFFAOYAZ
Standard InChI InChI=1S/BrO.K/c1-2;/q-1;+1
Standard InChIKey ORQYPOUSZINNCB-UHFFFAOYSA-N
ChemSpider 8074495
Properties
Chemical formula KBrO
Molar mass 135.00 g mol−1
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Potassium hypobromite, KBrO, is the potassium salt of hypobromous acid. It can be prepared by the reaction of bromine with aqueous potassium hydroxide solution at 0 °C or lower.[1][2] It has long been known as a strong oxidizing agent in solution,[3] but the solid trihydrate was not isolated until 1952.[2]

Notes and references

Notes

References

  1. Cotton, F. Albert; Wilkinson, Geoffrey Advanced Inorganic Chemistry, 5th ed.; Wiley-Interscience: New York, 1988; pp 563–67. ISBN 0-471-84997-9.
  2. 2.0 2.1 Scholder, R.; Krauss, K. Über Kristallisierte Alkalihypobromite. Z. Anorg. Allg. Chem. 1952, 268 (4–6), 279–90. DOI: 10.1002/zaac.19522680410.
  3. Tomíček, O.; Jašek, M. Volumetric Determinations in Strongly Alkaline Solutions. III. The Titration of Thallium and Cerium with Hypobromite. J. Am. Chem. Soc. 1935, 57 (12), 2409–11. DOI: 10.1021/ja01315a026.

External links

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