Potassium perbromate

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Potassium perbromate
IUPAC name Potassium perbromate
Other names Potassium bromate(VII)
Identifiers
InChI InChI=1/BrHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
InChIKey VXLUZERCXISKBW-REWHXWOFAE
Standard InChI InChI=1S/BrHO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
Standard InChIKey VXLUZERCXISKBW-UHFFFAOYSA-M
CAS number [22207-96-1]
ChemSpider 9369771
Properties[1][2]
Chemical formula KBrO4
Molar mass 183.00 g mol−1
Melting point

275–280 °C decomp.

Solubility in water ca. 3.7 g/100 g
Thermochemistry[2]
Std enthalpy of formation ΔfHo298 −287.6 kJ mol−1
Std Gibbs energy of formation ΔfGo298 −174.1 kJ mol−1
Standard molar entropy So298 170 J K−1 mol−1
Related compounds
Other anions Potassium perchlorate
Potassium periodate
Other cations Lithium perbromate
Sodium perbromate
Rubidium perbromate
Caesium perbromate
Other compounds Potassium bromide
Potassium hypobromite
Potassium bromite
Potassium bromate
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Potassium bromate, KBrO4, is the potassium salt of perbromic acid. It is prepared by the neutralization of perbromic acid with potassium carbonate or potassium hydroxide.[1][3]

Notes and references

Notes

References

  1. 1.0 1.1 Ukeles, S. D.; Freiberg, M. Bromine, Inorganic Compounds. In Kirk-Othmer Encyclopedia of Chemical Technology; John Wiley: New York, 2002. DOI: 10.1002/0471238961.021815131001031.
  2. 2.0 2.1 Greenwood, Norman N.; Earnshaw, A. Chemistry of the Elements; Pergamon: Oxford, 1984; pp 1020–22. ISBN 0-08-022057-6.
  3. Appelman, E. H. Perbromic acid and potassium perbromate. Inorg. Synth. 1972, 13, 1–9. DOI: 10.1002/9780470132449.ch1.

Further reading

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