Barium manganate

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Barium manganate
IUPAC name barium manganate(VI)
Identifiers
CAS number [7787-35-1]
EC number 232-109-6
ChemSpider 2341155
Properties[1]
Chemical formula BaMnO4
Molar mass 256.26 g mol−1
Appearance grey-green powder
Density 4.85 g cm−3
Solubility in water insoluble
Hazards[2]
EU index number 056-002-00-7
GHS pictograms Acute Tox. 4 (oral, inhal.)
GHS signal word WARNING
GHS hazard statements H302, H332
GHS precautionary statements P261, P264, P270, P271, P301+312, P304+340, P330, P501
Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa)

Barium manganate, BaMnO4, is a grey-green solid, insoluble in most common solvents. It is used as an oxidizing agent in organic synthesis.[3][4][5]

References

  1. CRC Handbook of Chemistry and Physics, 62nd ed.; Weast, Robert C., Ed.; CRC Press: Boca Raton, FL, 1981; p B-81. ISBN 0-8493-0462-8.
  2. Index no. 056-002-00-7 of Annex VI, Part 3, to Regulation (EC) No 1272/2008 of the European Parliament and of the Council of 16 December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006. OJEU L353, 31.12.2008, pp 1–1355 at p 438.
  3. Procter, G.; Ley, S. V.; Castle, G. H. Barium Manganate. In Encyclopedia of Reagents for Organic Synthesis; Paquette, L., Ed.; Wiley: New York, 2004. DOI: 10.1002/047084289.
  4. Firouzabadi, Habib; Mostafavipoor, Zohreh Barium Manganate. A Versatile Oxidant in Organic Synthesis. Bull. Chem. Soc. Jpn. 1983, 56 (3), 914–17. DOI: 10.1246/bcsj.56.914.
  5. Guziec, Frank S., Jr.; Murphy, Christopher J.; Cullen, Edward R. Thermal and photochemical studies of symmetrical and unsymmetrical dihydro-1,3,4-selenadiazoles. J. Chem. Soc., Perkin Trans. 1 1985, 107–13. DOI: 10.1039/P19850000107.

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