Metals in organic synthesis

NERM June 2 - 5, 2010 POTSDAM
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This symposium will cover the use of metals in organic synthesis. The session is planned for the morning of Thursday, June 3rd.

Sponsors

This session is sponsored by Materia - "Delivering Solutions through Olefin Metathesis Catalyst Technology". Materia is a privately held corporation headquartered in Pasadena, California with additional manufacturing facilities in Huntsville, Texas.

Symposium organizer

• Prof. Steven T. Diver is Professor and Director of Graduate Studies in the Department of Chemistry at SUNY Buffalo. He studies alkyne chemistry, such as alkyne metathesis and synthesis of enynes.

Invited speakers

• Prof. Matthias Brewer, University of Vermont: "Lewis acid mediated ring fragmentations: A concise route to polycyclic 2,5-dihydropyrroles from α-silyloxy ketones".
• Prof. Kian Tan, Boston College: "Regio- and Stereoselective Hydroformylation Using a Catalytic Directing Group".
• Prof. Daniel Clark, Syracuse University: "Transformations utilizing ruthenium hydrides for the synthesis of conjugated systems".
• Ms. Monissa Paderes (Chemler group), University at Buffalo: "Mechanism of the copper-promoted intramolecular aminooxygenation of alkenes".
• Mr. Derek Schipper (research group of the late Prof. Keith Fagnou), University of Ottawa.

Prof. Tan	Prof. Clark	Ms. Paderes	Mr. Schipper	Prof. Brewer

Program

Thursday, June 3, 9:00 AM - 12:20 PM

Organic Chemistry- Session A, Metals in Organic Synthesis

Kellas 104

Organizers: Steven Diver, Fehmi Damkaci

Presider: Steven Diver

9:00 Introductory Remarks

9:05 171 Transformations Utilizing Ruthenium Hydrides for the Synthesis of Conjugated Systems. Daniel A. Clark, Syracuse University

9:30 172 Mechanism of the Copper-Promoted Intramolecular Aminooxygenation of Alkenes. Monissa C. Paderes, Jerome B. Keister and Sherry R. Chemler, University at Buffalo, The State University of New York

9:55 173 Regio- and Stereoselective Hydroformylation Using a Catalytic Directing Group. Kian Tan, Boston College

10:35 Intermission

10:45 174 Asymmetric Ring-Expanding Enyne Metathesis. William S. Karnofel and Steven T. Diver, University at Buffalo

11:10 175 Lewis Acid Mediated Ring Fragmentations: A Concise Route to Polycyclic 2,5-Dihydropyrroles from a-SilyloxyKetones. Matthias Brewer, Qiufeng Huang, Cristian Draghici and Ali Bayir, The University of Vermont

11:50 176 Rhodium(III)-Catalyzed Intermolecular Hydroarylation of Alkynes. Derek J. Schipper, Marieke Hutchinson and Keith Fagnou, University of Ottawa

12:15 Concluding Remarks